Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine
Berger R, Mitzel NW (2010)
JOURNAL OF MOLECULAR STRUCTURE 978(1-3): 205-208.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Abstract / Bemerkung
The gas-phase structure of tris(trifluoromethyl)arsine (As(CF3)(3)) at ambient temperature has been reinvestigated by means of electron diffraction. Substantial higher accuracy in structural parameters compared to the previous investigation has been achieved. In contrast to the previously reported C-3v structure we found C-3 symmetry. Selected r(a3,1) structure parameters are: As-C = 2.007(2) angstrom; C-As-C = 95.5(3)degrees. The experimental structure parameters are compared to parameters obtained in HF/TZVPP and MP2/TZVPP calculations, the latter being in excellent agreement with the experimental structure. (C) 2010 Elsevier B.V. All rights reserved.
Stichworte
Gas electron diffraction;
Ab-initio;
calculations;
Arsine;
Trifluoromethyl
Erscheinungsjahr
2010
Zeitschriftentitel
JOURNAL OF MOLECULAR STRUCTURE
Band
978
Ausgabe
1-3
Seite(n)
205-208
ISSN
0022-2860
Page URI
https://pub.uni-bielefeld.de/record/1794236
Zitieren
Berger R, Mitzel NW. Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE. 2010;978(1-3):205-208.
Berger, R., & Mitzel, N. W. (2010). Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE, 978(1-3), 205-208. https://doi.org/10.1016/j.molstruc.2010.02.018
Berger, Raphael, and Mitzel, Norbert W. 2010. “Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine”. JOURNAL OF MOLECULAR STRUCTURE 978 (1-3): 205-208.
Berger, R., and Mitzel, N. W. (2010). Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE 978, 205-208.
Berger, R., & Mitzel, N.W., 2010. Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE, 978(1-3), p 205-208.
R. Berger and N.W. Mitzel, “Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine”, JOURNAL OF MOLECULAR STRUCTURE, vol. 978, 2010, pp. 205-208.
Berger, R., Mitzel, N.W.: Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE. 978, 205-208 (2010).
Berger, Raphael, and Mitzel, Norbert W. “Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine”. JOURNAL OF MOLECULAR STRUCTURE 978.1-3 (2010): 205-208.
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