Polymer Carpets

Amin I, Steenackers M, Zhang N, Beyer A, Zhang X, Pirzer T, Hugel T, Jordan R, Gölzhäuser A (2010)
SMALL 6(15): 1623-1630.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Amin, IhsanUniBi; Steenackers, Marin; Zhang, Ning; Beyer, AndréUniBi ; Zhang, XinaghuiUniBi; Pirzer, Tobias; Hugel, Thorsten; Jordan, Rainer; Gölzhäuser, ArminUniBi
Abstract / Bemerkung
The fabrication of defined polymer objects of reduced dimensions such as polymer-coated nanoparticles (zero-dimensional (OD)) cylindrical brushes (ID), and polymer membranes (2D), is currently the subject of intense research. In particular, ultrathin polymer membranes with high aspect ratios are being discussed as novel materials for miniaturized sensors because they would provide extraordinary sensitivity and dynamic range when sufficient mechanical stability can be combined with flexibility and chemical functionality. Unlike current approaches that rely on crosslinking of polymer layers for stabilization, this report presents the preparation of a new class of polymer material, so-called "polymer carpets," a freestanding polymer brush grown by surface-initiated polymerization on a crosslinked l-nm-thick monolayer. The solid-supported, as well as freestanding, polymer carpets are found to be mechanically robust and to react instantaneously and reversibly to external stimuli by buckling. The carpet mechanics and the dramatic changes of the film properties (optical, wetting) upon chemical stimuli are investigated in detail as they allow the development of completely new integrated micro-/nanotechnology devices.
polymer carpets; self-assembled monolayers; free-standing membranes; polymer brushes; nanosheets
Page URI


Amin I, Steenackers M, Zhang N, et al. Polymer Carpets. SMALL. 2010;6(15):1623-1630.
Amin, I., Steenackers, M., Zhang, N., Beyer, A., Zhang, X., Pirzer, T., Hugel, T., et al. (2010). Polymer Carpets. SMALL, 6(15), 1623-1630. https://doi.org/10.1002/smll.201000448
Amin, Ihsan, Steenackers, Marin, Zhang, Ning, Beyer, André, Zhang, Xinaghui, Pirzer, Tobias, Hugel, Thorsten, Jordan, Rainer, and Gölzhäuser, Armin. 2010. “Polymer Carpets”. SMALL 6 (15): 1623-1630.
Amin, I., Steenackers, M., Zhang, N., Beyer, A., Zhang, X., Pirzer, T., Hugel, T., Jordan, R., and Gölzhäuser, A. (2010). Polymer Carpets. SMALL 6, 1623-1630.
Amin, I., et al., 2010. Polymer Carpets. SMALL, 6(15), p 1623-1630.
I. Amin, et al., “Polymer Carpets”, SMALL, vol. 6, 2010, pp. 1623-1630.
Amin, I., Steenackers, M., Zhang, N., Beyer, A., Zhang, X., Pirzer, T., Hugel, T., Jordan, R., Gölzhäuser, A.: Polymer Carpets. SMALL. 6, 1623-1630 (2010).
Amin, Ihsan, Steenackers, Marin, Zhang, Ning, Beyer, André, Zhang, Xinaghui, Pirzer, Tobias, Hugel, Thorsten, Jordan, Rainer, and Gölzhäuser, Armin. “Polymer Carpets”. SMALL 6.15 (2010): 1623-1630.

11 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Mussel-Inspired Polymer Carpets: Direct Photografting of Polymer Brushes on Polydopamine Nanosheets for Controlled Cell Adhesion.
Hafner D, Ziegler L, Ichwan M, Zhang T, Schneider M, Schiffmann M, Thomas C, Hinrichs K, Jordan R, Amin I., Adv Mater 28(7), 2016
PMID: 26671880
Carbon Nanomembranes.
Turchanin A, Gölzhäuser A., Adv Mater 28(29), 2016
PMID: 27281234
Microporous polymer network films covalently bound to gold electrodes.
Becker D, Heidary N, Horch M, Gernert U, Zebger I, Schmidt J, Fischer A, Thomas A., Chem Commun (Camb) 51(20), 2015
PMID: 25672669
Amino-terminated biphenylthiol self-assembled monolayers as highly reactive molecular templates.
Meyerbroeker N, Waske P, Zharnikov M., J Chem Phys 142(10), 2015
PMID: 25770508
Ultrathin, freestanding, stimuli-responsive, porous membranes from polymer hydrogel-brushes.
Kang C, Ramakrishna SN, Nelson A, Cremmel CV, vom Stein H, Spencer ND, Isa L, Benetti EM., Nanoscale 7(30), 2015
PMID: 26169114
Carbon nanomembranes (CNMs) supported by polymer: mechanics and gas permeation.
Ai M, Shishatskiy S, Wind J, Zhang X, Nottbohm CT, Mellech N, Winter A, Vieker H, Qiu J, Dietz KJ, Gölzhäuser A, Beyer A., Adv Mater 26(21), 2014
PMID: 24535992
Micro-contact printing of graphene oxide nanosheets for fabricating patterned polymer brushes.
Xiao P, Gu J, Chen J, Zhang J, Xing R, Han Y, Fu J, Wang W, Chen T., Chem Commun (Camb) 50(54), 2014
PMID: 24836977
A microcontact printing induced supramolecular self-assembled photoactive surface for patterning polymer brushes.
Xiao P, Gu J, Chen J, Han D, Zhang J, Cao H, Xing R, Han Y, Wang W, Chen T., Chem Commun (Camb) 49(95), 2013
PMID: 24150764
Patterned polymer brushes.
Chen T, Amin I, Jordan R., Chem Soc Rev 41(8), 2012
PMID: 22234473
Patterned polymer carpets.
Amin I, Steenackers M, Zhang N, Schubel R, Beyer A, Gölzhäuser A, Jordan R., Small 7(5), 2011
PMID: 21370466
Ultrahigh-aspect ratio microfiber-furs as plant-surface mimics derived from teeth.
Fik CP, Meuris M, Salz U, Bock T, Tiller JC., Adv Mater 23(31), 2011
PMID: 21766346

42 References

Daten bereitgestellt von Europe PubMed Central.

Ultrasonic deposition of high-selectivity nanoporous carbon membranes
Shiflett MB, Foley HC., Science 285(5435), 1999
PMID: 10489366

Rogalski, Progr. Quant. Electron 27(), 2003

Wang, Nano Lett. 2(), 2002

Huck, Angew. Chem. Int. Ed. 39(), 2000

Mallwitz, Adv. Mater. 17(), 2005

Mallwitz, Angew. Chem. Int. Ed. 40(), 2001

Eck, Adv. Mater. 17(), 2005

Turchanin, Adv. Mater. 21(), 2009

Nardin, Langmuir 16(), 2000
Quantifying glass transition behavior in ultrathin free-standing polymer films
Mattsson J, Forrest JA, Borjesson L., Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics 62(4 Pt B), 2000
PMID: 11089081
Freely suspended nanocomposite membranes as highly sensitive sensors.
Jiang C, Markutsya S, Pikus Y, Tsukruk VV., Nat Mater 3(10), 2004
PMID: 15448680

Ko, Chem. Mater. 17(), 2005

Watanabe, Bull. Chem. Soc. Jpn. 80(), 2007
Robust free-standing nanomembranes of organic/inorganic interpenetrating networks.
Vendamme R, Onoue SY, Nakao A, Kunitake T., Nat Mater 5(6), 2006
PMID: 16715083

Carlen, Appl. Phys. Lett. 89(), 2006
Fabrication of single-walled carbon-nanotube-based pressure sensors.
Stampfer C, Helbling T, Obergfell D, Schoberle B, Tripp MK, Jungen A, Roth S, Bright VM, Hierold C., Nano Lett. 6(2), 2006
PMID: 16464041
Nanostructured artificial nacre.
Tang Z, Kotov NA, Magonov S, Ozturk B., Nat Mater 2(6), 2003
PMID: 12764359

Yosuke, Adv. Mater. 21(), 2009

Ducker, Soft Matter 4(), 2008



Sevick, Macromolecules 27(), 1994

Kumar, Prog. Polym. Sci. 32(), 2007

Steenackers, Adv. Mater. 21(), 2009
Structured polymer grafts on diamond.
Steenackers M, Lud SQ, Niedermeier M, Bruno P, Gruen DM, Feulner P, Stutzmann M, Garrido JA, Jordan R., J. Am. Chem. Soc. 129(50), 2007
PMID: 18034481

Zhang, Macromolecules 42(), 2009
Microstructured poly(2-oxazoline) bottle-brush brushes on nanocrystalline diamond.
Hutter NA, Reitinger A, Zhang N, Steenackers M, Williams OA, Garrido JA, Jordan R., Phys Chem Chem Phys 12(17), 2010
PMID: 20407707

Genzer, Soft Matter 2(), 2006

Groenewold, Physica A 298(), 2001

Huang, J. Mech. Phys. Solids 53(), 2005

Wilder, Macromolecules 39(), 2006

Williams, J. Phys. II 3(), 1993

Yeung, Macromolecules 26(), 1993

Wang, Macromol. Rapid Commun. 25(), 2004

Deng, Macromol. Rapid Commun. 22(), 2001

Pimblott, J. Phys. Chem. B 104(), 2000

Vlassak, J. Mater. Res. 7(), 1992

Martins, Eur. Phys. J. Appl. Phys. 45(), 2009


Julthongpiput, Polymer 44(), 2003
Fully cross-linked and chemically patterned self-assembled monolayers.
Beyer A, Godt A, Amin I, Nottbohm CT, Schmidt C, Zhao J, Golzhauser A., Phys Chem Chem Phys 10(48), 2008
PMID: 19060967

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

PMID: 20635346
PubMed | Europe PMC

Suchen in

Google Scholar