Three different product types from reactions of lithiated cyclic aminals with trivalent organometal chlorides

Hellmann B, Kamps I, Mix A, Neumann B, Stammler H-G, Mitzel NW (2010)
CHEMICAL COMMUNICATIONS 46(35): 6536-6538.

Download
Es wurde kein Volltext hochgeladen. Nur Publikationsnachweis!
Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
The reaction of 2-lithio-1,3,5-trimethyl-1,3,5-triazacyclohexane with YCp2Cl leads to the formation of a donor-functionalised mono-anionic amide ligand, 1,3,5-trimethyl-2-(methylamidomethyl)- 1,3,5-triazacyclohexane, bonded to the YCp2 unit. The reaction involves a cleavage of the 1,3,5-triazacyclohexane ring and such a cleavage is also observed in the analogous reaction with (Me3C)(2)GaCl, where a MeN=CH- fragment is formed. No such cleavage occurs in the reaction of the related dilithiated bicyclic bis(3-methyl-1,3-diazacyclohex-1-yl)methane with YCpCl2 center dot 3thf, which affords a mixed lithium-yttrium organyl.
Erscheinungsjahr
Zeitschriftentitel
CHEMICAL COMMUNICATIONS
Band
46
Ausgabe
35
Seite(n)
6536-6538
ISSN
eISSN
PUB-ID

Zitieren

Hellmann B, Kamps I, Mix A, Neumann B, Stammler H-G, Mitzel NW. Three different product types from reactions of lithiated cyclic aminals with trivalent organometal chlorides. CHEMICAL COMMUNICATIONS. 2010;46(35):6536-6538.
Hellmann, B., Kamps, I., Mix, A., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2010). Three different product types from reactions of lithiated cyclic aminals with trivalent organometal chlorides. CHEMICAL COMMUNICATIONS, 46(35), 6536-6538. doi:10.1039/c0cc01830a
Hellmann, B., Kamps, I., Mix, A., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2010). Three different product types from reactions of lithiated cyclic aminals with trivalent organometal chlorides. CHEMICAL COMMUNICATIONS 46, 6536-6538.
Hellmann, B., et al., 2010. Three different product types from reactions of lithiated cyclic aminals with trivalent organometal chlorides. CHEMICAL COMMUNICATIONS, 46(35), p 6536-6538.
B. Hellmann, et al., “Three different product types from reactions of lithiated cyclic aminals with trivalent organometal chlorides”, CHEMICAL COMMUNICATIONS, vol. 46, 2010, pp. 6536-6538.
Hellmann, B., Kamps, I., Mix, A., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Three different product types from reactions of lithiated cyclic aminals with trivalent organometal chlorides. CHEMICAL COMMUNICATIONS. 46, 6536-6538 (2010).
Hellmann, Benjamin, Kamps, Ina, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Three different product types from reactions of lithiated cyclic aminals with trivalent organometal chlorides”. CHEMICAL COMMUNICATIONS 46.35 (2010): 6536-6538.

1 Zitation in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Silylation products of cyclic tri-aminal carbanions and their lithiation.
Sicking C, Mix A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 41(1), 2012
PMID: 22075546

24 References

Daten bereitgestellt von Europe PubMed Central.


Bojer, Angew. Chem. 119(), 2007

Köhn, Chem. Ber. 129(), 1996

Schlosser, Angew. Chem. 85(), 1973

Bauer, J. Am. Chem. Soc. 114(), 1992

Karsch, Chem. Ber. 129(), 1996

Köhler, Chem. Ber. 120(), 1987

Gessner, Angew. Chem. 119(), 2007

Strohmann, Angew. Chem. 119(), 2007

Arnold, Dalton Trans. (), 2002

Whisler, Angew. Chem. 116(), 2004

Strohmann, Chem.–Asian J. 3(), 2008

Kamps, Chem.–Eur. J. 15(), 2009

Kamps, Chem. Commun. (), 2009

Seebach, J. Org. Chem. 40(), 1975

Kamps, Dalton Trans. (), 2009

Mu, Organometallics 15(), 1996

Booij, Organometallics 8(), 1989

Ge, Organometallics 26(), 2007

Carter, J. Chem. Soc. C 2591(), 1968

Vasylyev, Vib. Spectrosc. 20(), 1999

Tazelaar, Organometallics 23(), 2004

Uhl, Z. Naturforsch., B 59(), 2004

Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

Quellen

PMID: 20714557
PubMed | Europe PMC

Suchen in

Google Scholar