Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion

Lissel, Manfred; Jansen in de Wal, Helmut; Neumann, Ronny

Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion

Lissel M, Jansen in de Wal H, Neumann R (1992)
Tetrahedron Letters 33(13): 1795-1798.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

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DOI

https://doi.org/10.1016/S0040-4039(00)91735-0

URN

urn:nbn:de:0070-pub-17848617

Autor*in

Lissel, Manfred^UniBi; Jansen in de Wal, Helmut; Neumann, Ronny

Einrichtung

Fakultät für Chemie

Abstract / Bemerkung

The H5PV2Mo10O40 heteropolyanion has been found to catalyse the highly selective aerobic oxidation of dialkylphenols to diphenoquinones and the oxidation of 2, 3, 5-trimethylphenol to the 2, 3, 5-trimethyl-1, 4-benzoquinone. The rate is highly dependent on the oxidation potential of the substrate and is proceeds by electron transfer from the phenol substrate to the heteropolyanion catalyst.

Stichworte

DIOXYGEN; PHENOL OXIDATION; HETEROPOLYANIONS

Erscheinungsjahr

1992

Zeitschriftentitel

Tetrahedron Letters

Band

Ausgabe

Seite(n)

1795-1798

ISSN

0040-4039

Page URI

https://pub.uni-bielefeld.de/record/1784861

Zitieren

Lissel M, Jansen in de Wal H, Neumann R. Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion. Tetrahedron Letters. 1992;33(13):1795-1798.

Lissel, M., Jansen in de Wal, H., & Neumann, R. (1992). Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion. Tetrahedron Letters, 33(13), 1795-1798. https://doi.org/10.1016/S0040-4039(00)91735-0

Lissel, Manfred, Jansen in de Wal, Helmut, and Neumann, Ronny. 1992. “Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion”. Tetrahedron Letters 33 (13): 1795-1798.

Lissel, M., Jansen in de Wal, H., and Neumann, R. (1992). Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion. Tetrahedron Letters 33, 1795-1798.

Lissel, M., Jansen in de Wal, H., & Neumann, R., 1992. Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion. Tetrahedron Letters, 33(13), p 1795-1798.

M. Lissel, H. Jansen in de Wal, and R. Neumann, “Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion”, Tetrahedron Letters, vol. 33, 1992, pp. 1795-1798.

Lissel, M., Jansen in de Wal, H., Neumann, R.: Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion. Tetrahedron Letters. 33, 1795-1798 (1992).

Lissel, Manfred, Jansen in de Wal, Helmut, and Neumann, Ronny. “Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion”. Tetrahedron Letters 33.13 (1992): 1795-1798.

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