A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex

Siemeling, Ulrich; Neumann, Beate; Stammler, Hans-Georg

A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex

Siemeling U, Neumann B, Stammler H-G (1994)
Zeitschrift für Naturforschung, B: Chemical Sciences 49(5): 683-686.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

Download

Stammler_011.pdf

URN

urn:nbn:de:0070-bipr-6328

Autor*in

Siemeling, Ulrich; Neumann, Beate^UniBi; Stammler, Hans-Georg^UniBi

Einrichtung

Fakultät für Chemie

Abstract / Bemerkung

The novel cyclopentadiene HMe4C5CH2CMe2py [py = 2-(4-tert-butyl)pyridyl] 2H has been prepared from tetramethylfulvene and lithiated 2-isopropyl-4-tert-butylpyridine. Lithiation of 2H with Bu n Li and subsequent reaction with FeCl2 yields the ferrocene (2) 2Fe, which crystallizes in the triclinic space group P (1) with a = 8.368(1), b = 8.468(1), c = 14.313(1) Å, [alpha] = 80.64(1), [beta] = 86.67(1), [gamma] = 80.12(1)° and V = 985.4(2) Å (3).

Stichworte

crystal structure; pyridyl-functionalized cyclopentadienes; pyridyl-functionalized ferrocene; Hemilabile cyclopentadienyl ligands

Erscheinungsjahr

1994

Zeitschriftentitel

Zeitschrift für Naturforschung, B: Chemical Sciences

Band

Ausgabe

Seite(n)

683-686

ISSN

0932-0776

Page URI

https://pub.uni-bielefeld.de/record/1774932

Zitieren

Siemeling U, Neumann B, Stammler H-G. A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex. Zeitschrift für Naturforschung, B: Chemical Sciences. 1994;49(5):683-686.

Siemeling, U., Neumann, B., & Stammler, H. - G. (1994). A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex. Zeitschrift für Naturforschung, B: Chemical Sciences, 49(5), 683-686.

Siemeling, Ulrich, Neumann, Beate, and Stammler, Hans-Georg. 1994. “A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex”. Zeitschrift für Naturforschung, B: Chemical Sciences 49 (5): 683-686.

Siemeling, U., Neumann, B., and Stammler, H. - G. (1994). A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex. Zeitschrift für Naturforschung, B: Chemical Sciences 49, 683-686.

Siemeling, U., Neumann, B., & Stammler, H.-G., 1994. A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex. Zeitschrift für Naturforschung, B: Chemical Sciences, 49(5), p 683-686.

U. Siemeling, B. Neumann, and H.-G. Stammler, “A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex”, Zeitschrift für Naturforschung, B: Chemical Sciences, vol. 49, 1994, pp. 683-686.

Siemeling, U., Neumann, B., Stammler, H.-G.: A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex. Zeitschrift für Naturforschung, B: Chemical Sciences. 49, 683-686 (1994).

Siemeling, Ulrich, Neumann, Beate, and Stammler, Hans-Georg. “A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex”. Zeitschrift für Naturforschung, B: Chemical Sciences 49.5 (1994): 683-686.

Alle Dateien verfügbar unter der/den folgenden Lizenz(en):

Copyright Statement: