Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene
Jutzi P, Becker A, Stammler H-G, Neumann B (1991)
Organometallics 10(6): 1647-1648.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Autor*in
Abstract / Bemerkung
The reaction of Me5C5GeCH(SiMe3)2 with LiC-(SiMe,)3 affords (Me3Si)3CGeCH(SiMe3)2 (2), the first unsymmetrically substituted dialkylgermylene, which is stable at ambient temperature. In the solid state, the germylene 2 is monomeric, whereas Lappert's germylene [(Me3Si)2CH]2Ge (1) shows a dimeric structure with a Ge=Ge double bond. Steric effects of the additional trimethylsilyl group in 2 are responsible for these drastic changes in the structure. The germylene Me3SiCH2GeCH(SiMe2)2 (3) decomposes at about -20° C.
Erscheinungsjahr
1991
Zeitschriftentitel
Organometallics
Band
10
Ausgabe
6
Seite(n)
1647-1648
ISSN
0276-7333
eISSN
1520-6041
Page URI
https://pub.uni-bielefeld.de/record/1774783
Zitieren
Jutzi P, Becker A, Stammler H-G, Neumann B. Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene. Organometallics. 1991;10(6):1647-1648.
Jutzi, P., Becker, A., Stammler, H. - G., & Neumann, B. (1991). Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene. Organometallics, 10(6), 1647-1648. https://doi.org/10.1021/om00052a002
Jutzi, Peter, Becker, Anke, Stammler, Hans-Georg, and Neumann, Beate. 1991. “Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene”. Organometallics 10 (6): 1647-1648.
Jutzi, P., Becker, A., Stammler, H. - G., and Neumann, B. (1991). Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene. Organometallics 10, 1647-1648.
Jutzi, P., et al., 1991. Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene. Organometallics, 10(6), p 1647-1648.
P. Jutzi, et al., “Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene”, Organometallics, vol. 10, 1991, pp. 1647-1648.
Jutzi, P., Becker, A., Stammler, H.-G., Neumann, B.: Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene. Organometallics. 10, 1647-1648 (1991).
Jutzi, Peter, Becker, Anke, Stammler, Hans-Georg, and Neumann, Beate. “Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene”. Organometallics 10.6 (1991): 1647-1648.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Copyright Statement:
Dieses Objekt ist durch das Urheberrecht und/oder verwandte Schutzrechte geschützt. [...]
Volltext(e)
Name
Access Level
Open Access
Zuletzt Hochgeladen
2019-09-06T08:48:13Z
MD5 Prüfsumme
610deab1184206f41dda2ecf7ef0f034
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Suchen in
Google Scholar