CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS

Jutzi P, WEGENER D, HURSTHOUSE MB (1991)
CHEMISCHE BERICHTE 124(2): 295-299.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Jutzi, PeterUniBi; WEGENER, D; HURSTHOUSE, MB
Abstract / Bemerkung
Crystalline Tl2B9H9C2Me2 (1) is obtained in the reaction of the carborane B9H11C2Me2 with two equivalents of thallium(I) ethanolate. An X-ray diffraction study of 1 shows - contrary to the expectation - the presence of isolated thallium ions and thalladicarbollide counteranions. The latter represent ion pairs composed of Tl(I)+ and B9H9C2Me2 inverted left perpendicular 2- units forming slipped icosahedrons. All possible Tl-Tl distances in 1 are too long for even weak attractive interactions, with one exception: A set of symmetry-equivalent cations possesses a Tl-Tl distance of 3.67 angstrom, which is in a range postulated by calculations for weak bonding.
Stichworte
DITHALLIUM DICARBOLLIDE; NONCLASSICAL TL(I)-TL(I); CRYSTAL STRUCTURE; INTERACTIONS; NONAHYDRO-2; THALLIUM; 3-DICARBA-CLOSO-DODECABORATE; 3-DIMETHYL-1-THALLA-2
Erscheinungsjahr
1991
Zeitschriftentitel
CHEMISCHE BERICHTE
Band
124
Ausgabe
2
Seite(n)
295-299
ISSN
0009-2940
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/1650303

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Jutzi P, WEGENER D, HURSTHOUSE MB. CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE. 1991;124(2):295-299.
Jutzi, P., WEGENER, D., & HURSTHOUSE, M. B. (1991). CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE, 124(2), 295-299. doi:10.1002/cber.19911240209
Jutzi, P., WEGENER, D., and HURSTHOUSE, M. B. (1991). CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE 124, 295-299.
Jutzi, P., WEGENER, D., & HURSTHOUSE, M.B., 1991. CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE, 124(2), p 295-299.
P. Jutzi, D. WEGENER, and M.B. HURSTHOUSE, “CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS”, CHEMISCHE BERICHTE, vol. 124, 1991, pp. 295-299.
Jutzi, P., WEGENER, D., HURSTHOUSE, M.B.: CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE. 124, 295-299 (1991).
Jutzi, Peter, WEGENER, D, and HURSTHOUSE, MB. “CRYSTALLINE TL2B2H9C2ME2 - SYNTHESIS AND SOLID-STATE STRUCTURE - A CONTRIBUTION TO THE PROBLEM OF TL(I)-TL(I) INTERACTIONS”. CHEMISCHE BERICHTE 124.2 (1991): 295-299.