(1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS
Jutzi P, SCHNITTGER J, HURSTHOUSE MB (1991)
CHEMISCHE BERICHTE 124(8): 1693-1697.
Zeitschriftenaufsatz
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Autor*in
Jutzi, PeterUniBi;
SCHNITTGER, J;
HURSTHOUSE, MB
Abstract / Bemerkung
Reaction of 1,1',3,3'-tetra-tert-butyl-5,5'-dihydropentafulvalenediyldilithium with stoichiometric amounts of thallium chloride affords the dinuclear complex (eta-5:eta-5-tBu4C10H4)Tl2 (2). Compound 2 is air- and moisture-sensitive, and photolabile. It crystallizes in the space group P1BAR and consists of two (cyclopentadienyl)thallium units which are connected by a central C-C bond and twisted against each other by 70-degrees. The monomeric units of 2 form a two-dimensional polymer with d zick-zack chain of Tl atoms and a periphery of substituted cyclopentadienyl ligands. Rather short Tl - Tl contacts of 3.760 and 3.998 angstrom are formed within a dimeric substructure. The geometry of the cyclopentadienyl ligands around the shortest Tl - Tl bond is similar to that predicted by the theory for weak Tl - Tl interactions.
Stichworte
3'-TETRA-TERT-BUTYL-DITHALLIUM;
FULVALENE COMPLEX;
THALLIUM;
(CYCLOPENTADIENYL)THALLIUM COMPLEX;
NONCLASSICAL TL(I)-TL(I) INTERACTIONS;
5;
5'-PENTAFULVALENE;
1;
1';
3
Erscheinungsjahr
1991
Zeitschriftentitel
CHEMISCHE BERICHTE
Band
124
Ausgabe
8
Seite(n)
1693-1697
ISSN
0009-2940
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/1649528
Zitieren
Jutzi P, SCHNITTGER J, HURSTHOUSE MB. (1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE. 1991;124(8):1693-1697.
Jutzi, P., SCHNITTGER, J., & HURSTHOUSE, M. B. (1991). (1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE, 124(8), 1693-1697. https://doi.org/10.1002/cber.19911240804
Jutzi, Peter, SCHNITTGER, J, and HURSTHOUSE, MB. 1991. “(1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS”. CHEMISCHE BERICHTE 124 (8): 1693-1697.
Jutzi, P., SCHNITTGER, J., and HURSTHOUSE, M. B. (1991). (1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE 124, 1693-1697.
Jutzi, P., SCHNITTGER, J., & HURSTHOUSE, M.B., 1991. (1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE, 124(8), p 1693-1697.
P. Jutzi, J. SCHNITTGER, and M.B. HURSTHOUSE, “(1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS”, CHEMISCHE BERICHTE, vol. 124, 1991, pp. 1693-1697.
Jutzi, P., SCHNITTGER, J., HURSTHOUSE, M.B.: (1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS. CHEMISCHE BERICHTE. 124, 1693-1697 (1991).
Jutzi, Peter, SCHNITTGER, J, and HURSTHOUSE, MB. “(1,1',3,3'-TETRA-TERT-BUTYL-5,5'-PENTAFULVALENE)DITHALLIUM - SYNTHESIS AND CRYSTAL-STRUCTURE - A CONTRIBUTION TO THE DISCUSSION OF NONCLASSICAL TL(I)-TL(I) INTERACTIONS”. CHEMISCHE BERICHTE 124.8 (1991): 1693-1697.
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