REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4)

Müller A, DORING J (1991)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 595(1): 251-274.

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DOI
Autor*in
Müller, AchimUniBi ; DORING, J
Einrichtung
Fakultät für Chemie
Abstract / Bemerkung
The novel cluster-compounds Na6[V18O42H9(VO4)].21 H2O, (NH4)8[V18O42(SO4)].25 H2O, K6[V15As6O42(H2O)].8 H2O, (NH4)6[V14As8O42(SO3)], (NH4)6[V14As8O42(SO4)] and [N(CH3)4]4[V14As8O42(H2O)] were prepared and characterized by IR- and UV/Vis/NIR-spectroscopy, magnetic measurements and complete crystal structure analysis. For structural data see Inhaltsubersicht. Topological relations to the rhombicuboctahedron spanned by 24 O-atoms of the genuine hypothetical alpha-Keggin ion, at which the square planes are capped by V = O or As2O groups, are discussed. Of particular interest are the "extended" Keggin ions [V18O42(X)]n- (X = SO4, VO4), (formaly derived from the hypothetical genuine alpha-Keggin ion by addition of six V = O groups) which have quite different electron populations in spite of the same structure of their cluster shells.
Stichworte
ANALYSES; CRYSTAL STRUCTURE; UV/VIS/NIR DATA; IR; STRUCTURE; KEGGIN; CLUSTER COMPOUNDS; MAGNETIC DATA; REDUCED SUBSTITUTED OCTADECAVANADATES
Erscheinungsjahr
1991
Zeitschriftentitel
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Band
595
Ausgabe
1
Seite(n)
251-274
ISSN
0044-2313
eISSN
1521-3749
Page URI
https://pub.uni-bielefeld.de/record/1649274

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Müller A, DORING J. REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4). ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 1991;595(1):251-274.
Müller, A., & DORING, J. (1991). REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4). ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 595(1), 251-274. https://doi.org/10.1002/zaac.19915950124
Müller, Achim, and DORING, J. 1991. “REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4)”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 595 (1): 251-274.
Müller, A., and DORING, J. (1991). REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4). ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 595, 251-274.
Müller, A., & DORING, J., 1991. REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4). ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 595(1), p 251-274.
A. Müller and J. DORING, “REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4)”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 595, 1991, pp. 251-274.
Müller, A., DORING, J.: REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4). ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 595, 251-274 (1991).
Müller, Achim, and DORING, J. “REDUCED CLUSTERS WITH REMARKABLE TOPOLOGICAL AND ELECTRONIC-PROPERTIES OF THE TYPE OF [V18O42(X)]N-(X=SO4,VO4) WITH TD-SYMMETRY AND RELATED CLUSTERS [V(18-P)AS2PO42(X)]M-(X=SO3,SO4,H2O-P=3,4)”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 595.1 (1991): 251-274.
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