Functionalized cyclopentadienes: Synthesis of 1,2,3,4,5-pentaallylcyclopentadiene and 1,2,3,4-tetraallylcyclopentadiene

Batz C, Jutzi P (1996)
SYNTHESIS-STUTTGART (11): 1296-+.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The synthesis of new penta- and tetraallylated cyclopentadienes is described. The title compounds 1a and 2a can be synthesized in a one-pot procedure from cyclopentadiene with a tenfold excess of both sodium hydride and allyl bromide under phase-transfer catalytical conditions. They are obtained in a mixture with their isomers from which they call be separated by metallation using potassium hydride giving the corresponding cyclopentadienides. Thus, these compounds are suitable candidates for the synthesis of multifunctionalizable organometallic systems.
Stichworte
tetra- and pentaallycyclopentadiene; multifunctionalizable ligands; functionalized cyclopentadienes; phase transfer catalysis
Erscheinungsjahr
1996
Zeitschriftentitel
SYNTHESIS-STUTTGART
Ausgabe
11
Seite(n)
1296-+
ISSN
0039-7881
Page URI
https://pub.uni-bielefeld.de/record/1638038

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Batz C, Jutzi P. Functionalized cyclopentadienes: Synthesis of 1,2,3,4,5-pentaallylcyclopentadiene and 1,2,3,4-tetraallylcyclopentadiene. SYNTHESIS-STUTTGART. 1996;(11):1296-+.
Batz, C., & Jutzi, P. (1996). Functionalized cyclopentadienes: Synthesis of 1,2,3,4,5-pentaallylcyclopentadiene and 1,2,3,4-tetraallylcyclopentadiene. SYNTHESIS-STUTTGART(11), 1296-+.
Batz, C., and Jutzi, P. (1996). Functionalized cyclopentadienes: Synthesis of 1,2,3,4,5-pentaallylcyclopentadiene and 1,2,3,4-tetraallylcyclopentadiene. SYNTHESIS-STUTTGART, 1296-+.
Batz, C., & Jutzi, P., 1996. Functionalized cyclopentadienes: Synthesis of 1,2,3,4,5-pentaallylcyclopentadiene and 1,2,3,4-tetraallylcyclopentadiene. SYNTHESIS-STUTTGART, (11), p 1296-+.
C. Batz and P. Jutzi, “Functionalized cyclopentadienes: Synthesis of 1,2,3,4,5-pentaallylcyclopentadiene and 1,2,3,4-tetraallylcyclopentadiene”, SYNTHESIS-STUTTGART, 1996, pp. 1296-+.
Batz, C., Jutzi, P.: Functionalized cyclopentadienes: Synthesis of 1,2,3,4,5-pentaallylcyclopentadiene and 1,2,3,4-tetraallylcyclopentadiene. SYNTHESIS-STUTTGART. 1296-+ (1996).
Batz, C, and Jutzi, Peter. “Functionalized cyclopentadienes: Synthesis of 1,2,3,4,5-pentaallylcyclopentadiene and 1,2,3,4-tetraallylcyclopentadiene”. SYNTHESIS-STUTTGART 11 (1996): 1296-+.

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