Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene

Bitterwolf TE, Ceccon A, Gambaro A, Ganis P, Kuck D, Manoli F, Rheingold AL, Valle G, Venzo A (1997)
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 (4): 735-742.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
DOI
Autor*in
Bitterwolf, T. E.; Ceccon, A.; Gambaro, A.; Ganis, P.; Kuck, DietmarUniBi; Manoli, F.; Rheingold, A. L.; Valle, G.; Venzo, A.
Einrichtung
Fakultät für Chemie > Industrielle Organische Chemie und Biotechnologie
Abstract / Bemerkung
The reaction of 4b,9,9a,10-tetrahydroindeno[1,2-a]indene, B, with Cr(CO)(6) in boiling mixtures of Bu2O and tetrahydrofuran (THF) (9: 1) affords two mono-complexes, one of which bears the Cr(CO)(3) group bonded to the convex side of the ligand (anti complex, B1) and the other inorganic unit to the concave side of B (syn complex, B2), After prolonged reaction times, two bis-complexes were isolated, the first having one Cr(CO)(3) group bonded to the convex side of B and the other to the concave side (syn,anti bis-complex, B3), and the second having both of the inorganic groups bonded to the convex side of B (anti,anti bis-complex, B4), The results of X-ray structural analysis support the hypothesis that the stereochemistry of the first and the second metallation reaction are related to the conformation of the ligand as induced by the steric interactions between aliphatic hydrogen atoms, The results confirm the existence of weak bonding interactions between oxygen atoms of the syn-Cr(CO)(3) carbonyl groups with vicinal benzene rings bearing an anti-Cr(CO)(3) group as well as methylene protons.
Erscheinungsjahr
1997
Zeitschriftentitel
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Ausgabe
4
Seite(n)
735-742
ISSN
0300-9580
eISSN
1364-5471
Page URI
https://pub.uni-bielefeld.de/record/1637389

Zitieren

Bitterwolf TE, Ceccon A, Gambaro A, et al. Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2. 1997;(4):735-742.
Bitterwolf, T. E., Ceccon, A., Gambaro, A., Ganis, P., Kuck, D., Manoli, F., Rheingold, A. L., et al. (1997). Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2(4), 735-742. https://doi.org/10.1039/a606716f
Bitterwolf, T. E., Ceccon, A., Gambaro, A., Ganis, P., Kuck, Dietmar, Manoli, F., Rheingold, A. L., Valle, G., and Venzo, A. 1997. “Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene”. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, no. 4: 735-742.
Bitterwolf, T. E., Ceccon, A., Gambaro, A., Ganis, P., Kuck, D., Manoli, F., Rheingold, A. L., Valle, G., and Venzo, A. (1997). Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 735-742.
Bitterwolf, T.E., et al., 1997. Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, (4), p 735-742.
T.E. Bitterwolf, et al., “Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene”, JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1997, pp. 735-742.
Bitterwolf, T.E., Ceccon, A., Gambaro, A., Ganis, P., Kuck, D., Manoli, F., Rheingold, A.L., Valle, G., Venzo, A.: Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2. 735-742 (1997).
Bitterwolf, T. E., Ceccon, A., Gambaro, A., Ganis, P., Kuck, Dietmar, Manoli, F., Rheingold, A. L., Valle, G., and Venzo, A. “Tricarbonylchromium complexes of centropolyindans .4. Physicochemical and structural characterization of anti-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene, syn-Cr(CO)(3)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene and syn,anti-[Cr(CO)(3)](2)-4b,9,9a,10-tetrahydroindeno[1,2-a]indene”. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 4 (1997): 735-742.
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Suchen in

Google Scholar