Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds

Kuck D (1997)
LIEBIGS ANNALEN-RECUEIL (6): 1043-1057.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
This article gives a comprehensive review of the synthetic development of centrohexacyclic organic compounds (''centrohexacyclanes'') during the past decade. With their unique feature of having molecular constitution that corresponds to the complete graph K-5, centrohexacyclanes represent the majority of the rare class of topologically nonplanar compounds. Starting from the few previously known organic, element-organic and inorganic K-5 compounds, the syntheses of various organic centrohexacyclanes are discussed, based mainly on three different strategies that have emanated from the chemistry of centropolyindanes: the propellane, fenestrate, and ''broken fenestrane'' routes. In addition, the first results of some targeted transformations of centrohexaindane, the T-d-symmetrical hexabenzoannelated centrohexaquinane, are presented.
Stichworte
spiro; fenestranes; propellanes; polycycles; cyclizations; annulation; compounds; topology; indanes
Erscheinungsjahr
1997
Zeitschriftentitel
LIEBIGS ANNALEN-RECUEIL
Ausgabe
6
Seite(n)
1043-1057
ISSN
0947-3440
Page URI
https://pub.uni-bielefeld.de/record/1636893

Zitieren

Kuck D. Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds. LIEBIGS ANNALEN-RECUEIL. 1997;(6):1043-1057.
Kuck, D. (1997). Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds. LIEBIGS ANNALEN-RECUEIL(6), 1043-1057.
Kuck, Dietmar. 1997. “Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds”. LIEBIGS ANNALEN-RECUEIL, no. 6: 1043-1057.
Kuck, D. (1997). Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds. LIEBIGS ANNALEN-RECUEIL, 1043-1057.
Kuck, D., 1997. Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds. LIEBIGS ANNALEN-RECUEIL, (6), p 1043-1057.
D. Kuck, “Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds”, LIEBIGS ANNALEN-RECUEIL, 1997, pp. 1043-1057.
Kuck, D.: Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds. LIEBIGS ANNALEN-RECUEIL. 1043-1057 (1997).
Kuck, Dietmar. “Centrohexacyclic or ''K-5'' molecules: Development of a growing family of topologically nonplanar organic compounds”. LIEBIGS ANNALEN-RECUEIL 6 (1997): 1043-1057.
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