Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands
Willner A, Hepp A, Mitzel NW (2008)
DALTON TRANSACTIONS (47): 6832-6842.
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Autor*in
Willner, Alexander;
Hepp, Alexander;
Mitzel, Norbert W.UniBi
Abstract / Bemerkung
The aminoalcohols MeNH(CH2)(2)OH (1), (BuNH)-Bu-t(CH2)(2)OH (2), MeNH(CH2)(3)OH (3), tBuNH(CH2)(3)OH (4) and MeNHCH2CMe2CH2OAlMe2 (5) have been reacted with AlMe3 to give the five corresponding aminoalkoxides of the general formula RNH-X-AlMe2 1a-5a (X = organic spacer between N and O). (BuNHCH2CMe2CH2OH)-Bu-t (6) reacts with AlMe3 to give [(BuNHCH2CMe2CH2OAlMe2)-Bu-t]center dot AlMe3 (6a center dot AlMe3). Analogous reactions of the aminoalcohols 1, 2, 3 and 4 with (AlBu3)-Bu-t, GaMe3 and (GaBu3)-Bu-t afforded the corresponding aminoalkoxides of the general formula RNH-X-MR2' 1b-4b (MR2' = (AlBu2)-Bu-t), 1c-4c (MR2' = GaMe2) and 1d-4d (MR2' = (GaBu2)-Bu-t). The compounds were characterised by NMR spectroscopy, elemental analyses and mass spectrometry. Crystal structures were determined for 3a, 5a, 6a center dot AlMe3, 3c, 3d, 2d and 4d. Compounds 3a and 5a dimerise via Al2O2 rings, while the amino-functions form intramolecular Al-N bonds. Compounds 3c and 3d form monomers with intramolecular Ga-N bonds. Compounds 2d and 4d are dimers via Ga2O2 rings but in contrast to 3a and 5a without formation of intramolecular Ga-N bonds. 6a center dot AlMe3 also forms a monomeric compound with intramolecular AlN bond and a further AlMe3 unit bonded to the O atom. The dynamic behaviour of 1d and 2d was investigated by variable-temperature NMR spectroscopy. Some compounds have different aggregation in solid and fluid phases.
Erscheinungsjahr
2008
Zeitschriftentitel
DALTON TRANSACTIONS
Ausgabe
47
Seite(n)
6832-6842
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/1636479
Zitieren
Willner A, Hepp A, Mitzel NW. Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands. DALTON TRANSACTIONS. 2008;(47):6832-6842.
Willner, A., Hepp, A., & Mitzel, N. W. (2008). Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands. DALTON TRANSACTIONS(47), 6832-6842. https://doi.org/10.1039/b811792f
Willner, Alexander, Hepp, Alexander, and Mitzel, Norbert W. 2008. “Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands”. DALTON TRANSACTIONS, no. 47: 6832-6842.
Willner, A., Hepp, A., and Mitzel, N. W. (2008). Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands. DALTON TRANSACTIONS, 6832-6842.
Willner, A., Hepp, A., & Mitzel, N.W., 2008. Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands. DALTON TRANSACTIONS, (47), p 6832-6842.
A. Willner, A. Hepp, and N.W. Mitzel, “Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands”, DALTON TRANSACTIONS, 2008, pp. 6832-6842.
Willner, A., Hepp, A., Mitzel, N.W.: Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands. DALTON TRANSACTIONS. 6832-6842 (2008).
Willner, Alexander, Hepp, Alexander, and Mitzel, Norbert W. “Organo-aluminium and -gallium complexes with omega-NH-functional alkoxide ligands”. DALTON TRANSACTIONS 47 (2008): 6832-6842.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
1 Zitation in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Exploring Planar-Chiral Amino Siloxides.
Golz C, Steffen P, Strohmann C., Angew Chem Int Ed Engl 56(28), 2017
PMID: 28504830
Golz C, Steffen P, Strohmann C., Angew Chem Int Ed Engl 56(28), 2017
PMID: 28504830
47 References
Daten bereitgestellt von Europe PubMed Central.
Basharat, Dalton Trans. (), 2008
Schumann, Polyhedron 9(), 1990
Pohl, J. Cryst. Growth 107(), 1991
Schumann, Eur. J. Solid State Inorg. Chem. 29(), 1992
Schumann, Z. Anorg. Allg. Chem. 627(), 2001
Schumann, Organometallics 22(), 2003
Schumann, Z. Anorg. Allg. Chem. 632(), 2006
Lewiński, Organometallics 24(), 2005
Eisenhardt, Adv. Synth. Catal. 345(), 2003
Schumann, Tetrahedron Lett. 42(), 2001
Schumann, Z. Anorg. Allg. Chem. 628(), 2002
Schumann, Tetrahedron Lett. 43(), 2002
Gelman, Synthesis (), 2001
Gelman, Inorg. Chim. Acta 334(), 2002
Jaber, Eur. J. Org. Chem. (), 2002
Gotsov, Synlett (), 2002
Shenglof, Synthesis (), 2003
Jaber, J. Heterocycl. Chem. 40(), 2003
Schumann, Synlett (), 2003
Beachley, Inorg. Chem. 15(), 1976
Kumar, Organometallics 13(), 1994
Hoffmann, Justus Liebigs Ann. Chem. 629(), 1960
Hogerheide, Organometallics 14(), 1995
Atwood, Organometallics 15(), 1996
Atwood, Organometallics 15(), 1996
Thiele, J. Organomet. Chem. 540(), 1997
Hecht, Z. Anorg. Allg. Chem. 624(), 1998
Gelbrich, J. Organomet. Chem. 595(), 2000
Hecht, Z. Anorg. Allg. Chem. 626(), 2000
McMahon, J. Chem. Soc., Dalton Trans. (), 1998
Francis, J. Chem. Soc., Dalton Trans. (), 1998
Francis, Organometallics 18(), 1999
Lewiński, Eur. J. Inorg. Chem. (), 2001
Lewiński, Organometallics 22(), 2003
Lewiński, Organometallics 23(), 2004
Basharat, J. Organomet. Chem. 693(), 2008
Basharat, Dalton Trans. (), 2004
Carmalt, Coord. Chem. Rev. 250(), 2006
Mitzel, Z. Naturforsch., B: Chem. Sci. 58(), 2003
Koepke, J. Org. Chem. 44(), 1979
Deyrup, J. Org. Chem. 34(), 1969
Mannich, Ber. Dtsch. Chem. Ges. 65(), 1932
Mannich, Ber. Dtsch. Chem. Ges. 65(), 1932
Gaines, Inorg. Synth. 15(), 1974
Lehmkuhl, Justus Liebigs Ann. Chem. (), 1973
Schwering, J. Organomet. Chem. 91(), 1975
Farrugia, J. Appl. Crystallogr. 30(), 1997
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