Rare-earth metal hydroxylamide complexes

Venugopal A, Hepp A, Pape T, Mix A, Mitzel NW (2008)
DALTON TRANSACTIONS (46): 6628-6633.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The rare-earth metal hydroxylamide compound Y[N(SiHMe2)(2)](2)[ONBn2][THF] (1) was prepared by the silylamide elimination pathway from the reaction of N, N-dibenzylhydroxylamine, Bn2NOH (Bn = CH2C6H5), with Y[ N(SiHMe2)(2)](3)[THF](2) and was characterised by multinuclear NMR spectroscopy and elemental analysis. The compounds [Cp2Y(ONBn2)](2) (2a) [Cp2Sm(ONBn2)](2) (2b) were obtained by the reactions of MCp3 (M = Y, Sm) with Bn2NOH. The trinuclear compound Cp5Y3[ON(Me)CH2CH2(Me)NO](2) (3) was obtained by the reaction of YCp3 and the bishydroxylamine HON(Me)CH2CH2(Me)NOH. 2a, 2b and 3 were characterised by NMR spectroscopy, single-crystal X-ray diffraction and elemental analysis. In all these complexes side-on-coordination of the hydroxylamide units was observed. The compounds are of dynamic nature in solution.
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DALTON TRANSACTIONS
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46
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6628-6633
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Venugopal A, Hepp A, Pape T, Mix A, Mitzel NW. Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS. 2008;(46):6628-6633.
Venugopal, A., Hepp, A., Pape, T., Mix, A., & Mitzel, N. W. (2008). Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS(46), 6628-6633. doi:10.1039/b810234a
Venugopal, A., Hepp, A., Pape, T., Mix, A., and Mitzel, N. W. (2008). Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS, 6628-6633.
Venugopal, A., et al., 2008. Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS, (46), p 6628-6633.
A. Venugopal, et al., “Rare-earth metal hydroxylamide complexes”, DALTON TRANSACTIONS, 2008, pp. 6628-6633.
Venugopal, A., Hepp, A., Pape, T., Mix, A., Mitzel, N.W.: Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS. 6628-6633 (2008).
Venugopal, Ajay, Hepp, Alexander, Pape, Tania, Mix, Andreas, and Mitzel, Norbert W. “Rare-earth metal hydroxylamide complexes”. DALTON TRANSACTIONS 46 (2008): 6628-6633.

1 Zitation in Europe PMC

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Structural variations and molecular dynamics of rare-earth metal complexes with the N,N-bis(2-{pyrid-2-yl}ethyl)hydroxylaminato ligand.
Hellmann BJ, Venugopal A, Mix A, Neumann B, Stammler HG, Willner A, Pape T, Hepp A, Mitzel NW., Chemistry 15(43), 2009
PMID: 19774565

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