Rare-earth metal hydroxylamide complexes
Venugopal A, Hepp A, Pape T, Mix A, Mitzel NW (2008)
DALTON TRANSACTIONS (46): 6628-6633.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Venugopal, Ajay;
Hepp, Alexander;
Pape, Tania;
Mix, AndreasUniBi;
Mitzel, Norbert W.UniBi
Abstract / Bemerkung
The rare-earth metal hydroxylamide compound Y[N(SiHMe2)(2)](2)[ONBn2][THF] (1) was prepared by the silylamide elimination pathway from the reaction of N, N-dibenzylhydroxylamine, Bn2NOH (Bn = CH2C6H5), with Y[ N(SiHMe2)(2)](3)[THF](2) and was characterised by multinuclear NMR spectroscopy and elemental analysis. The compounds [Cp2Y(ONBn2)](2) (2a) [Cp2Sm(ONBn2)](2) (2b) were obtained by the reactions of MCp3 (M = Y, Sm) with Bn2NOH. The trinuclear compound Cp5Y3[ON(Me)CH2CH2(Me)NO](2) (3) was obtained by the reaction of YCp3 and the bishydroxylamine HON(Me)CH2CH2(Me)NOH. 2a, 2b and 3 were characterised by NMR spectroscopy, single-crystal X-ray diffraction and elemental analysis. In all these complexes side-on-coordination of the hydroxylamide units was observed. The compounds are of dynamic nature in solution.
Erscheinungsjahr
2008
Zeitschriftentitel
DALTON TRANSACTIONS
Ausgabe
46
Seite(n)
6628-6633
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/1636472
Zitieren
Venugopal A, Hepp A, Pape T, Mix A, Mitzel NW. Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS. 2008;(46):6628-6633.
Venugopal, A., Hepp, A., Pape, T., Mix, A., & Mitzel, N. W. (2008). Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS(46), 6628-6633. https://doi.org/10.1039/b810234a
Venugopal, Ajay, Hepp, Alexander, Pape, Tania, Mix, Andreas, and Mitzel, Norbert W. 2008. “Rare-earth metal hydroxylamide complexes”. DALTON TRANSACTIONS, no. 46: 6628-6633.
Venugopal, A., Hepp, A., Pape, T., Mix, A., and Mitzel, N. W. (2008). Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS, 6628-6633.
Venugopal, A., et al., 2008. Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS, (46), p 6628-6633.
A. Venugopal, et al., “Rare-earth metal hydroxylamide complexes”, DALTON TRANSACTIONS, 2008, pp. 6628-6633.
Venugopal, A., Hepp, A., Pape, T., Mix, A., Mitzel, N.W.: Rare-earth metal hydroxylamide complexes. DALTON TRANSACTIONS. 6628-6633 (2008).
Venugopal, Ajay, Hepp, Alexander, Pape, Tania, Mix, Andreas, and Mitzel, Norbert W. “Rare-earth metal hydroxylamide complexes”. DALTON TRANSACTIONS 46 (2008): 6628-6633.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
1 Zitation in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Structural variations and molecular dynamics of rare-earth metal complexes with the N,N-bis(2-{pyrid-2-yl}ethyl)hydroxylaminato ligand.
Hellmann BJ, Venugopal A, Mix A, Neumann B, Stammler HG, Willner A, Pape T, Hepp A, Mitzel NW., Chemistry 15(43), 2009
PMID: 19774565
Hellmann BJ, Venugopal A, Mix A, Neumann B, Stammler HG, Willner A, Pape T, Hepp A, Mitzel NW., Chemistry 15(43), 2009
PMID: 19774565
23 References
Daten bereitgestellt von Europe PubMed Central.
Dove, Chem. Commun. (), 2005
Reactions of d0 group 4 amides with dioxygen. Preparation of unusual oxo aminoxy complexes and theoretical studies of their formation.
Wang R, Zhang XH, Chen SJ, Yu X, Wang CS, Beach DB, Wu YD, Xue ZL., J. Am. Chem. Soc. 127(14), 2005
PMID: 15810856
Wang R, Zhang XH, Chen SJ, Yu X, Wang CS, Beach DB, Wu YD, Xue ZL., J. Am. Chem. Soc. 127(14), 2005
PMID: 15810856
Mitzel, J. Chem. Soc., Dalton Trans. (), 1996
Wieghardt, Z. Anorg. Allg. Chem. 490(), 1982
Jana, Chem. Commun. (), 2006
Ullrich, Eur. J. Inorg. Chem. (), 2004
Bösing, Dalton Trans. (), 2008
Mitzel, Dalton Trans. (), 2004
Lustig, Angew. Chem. 113(), 2001
Lustig, Angew. Chem., Int. Ed. 40(), 2001
Evans, Chem. Commun. (), 2001
Venugopal, Dalton Trans. (), 2007
Bradley, J. Chem. Soc., Dalton Trans. (), 1973
Bradley, Polyhedron 2(), 1983
Evans, J. Am. Chem. Soc. 126(), 2003
Dietrich, Organometallics 24(), 2005
Mono(cyclopentadienyl) complexes of the rare-earth metals.
Arndt S, Okuda J., Chem. Rev. 102(6), 2002
PMID: 12059259
Arndt S, Okuda J., Chem. Rev. 102(6), 2002
PMID: 12059259
Herrmann, Z. Naturforsch., B: Chem. Sci. 49(), 1994
Chesman, Dalton Trans. (), 2007
Anwander, J. Chem. Soc., Dalton Trans. (), 1998
Rastätter, Chem.–Eur. J. 13(), 2007
Birmingham, J. Am. Chem. Soc. 78(), 1956
Kliegel, Acta Crystallogr., Sect. E: Struct. Rep. Online 58(), 2002
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Quellen
PMID: 19030626
PubMed | Europe PMC
Suchen in
Google Scholar