Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations
Merca A, Haupt ETK, Mitra T, Bögge H, Rehder D, Müller A (2007)
Chemistry - a European Journal 13(27): 7650-7658.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Merca, AliceUniBi;
Haupt, Erhard T. K.;
Mitra, TamoghnaUniBi;
Bögge, HartmutUniBi;
Rehder, Dieter;
Müller, AchimUniBi 
Einrichtung
Abstract / Bemerkung
Spherical capsules of the type [{(Mo)Mo-5}(12)[Mo-2(ligand)}(30)](n-) exhibiting 20 {Mo9O9} pores with crown ether functions allowed us to perform a sophisticated study of the title phenomenon based on synthetic work as well as NMR spectroscopy. The pores of the host system interact in solution specifically with guests that can be noncovalently bonded, such as formamidinium and acetamidinium cations, while having different affinities to the pores. The exchange between the guest species present in solution and in the pores was investigated, including, besides the extreme scenarios of complete pore closing and complete opening, that of stepwise pore plugging. Because of this option it was possible to model for the first time passive transmembrane cation transport based on gated pores/channels. These have the appropriate dimensions and can even adopt different structure flexibilities in response to different cations. The present investigation is based on related syntheses as well as on numerous detailed Li-7 NMR studies of Li+ transport/exchange equilibria in dependence of the pore environment/guest situations. One compound containing capsules with sulfate ligands (2) could be obtained in which all the pores are plugged with formamidinium cations and another corresponding one was obtained with additionally encapsulated Ca2+ ions (3); these were taken up after temporary release of some of the formamidinium plugs/guests upon short heating of the related solution.
Stichworte
polyoxometalates;
supramolecular chemistry;
NMR spectroscopy;
nanocapsules;
ion transport
Erscheinungsjahr
2007
Zeitschriftentitel
Chemistry - a European Journal
Band
13
Ausgabe
27
Seite(n)
7650-7658
ISSN
0947-6539
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/1631949
Zitieren
Merca A, Haupt ETK, Mitra T, Bögge H, Rehder D, Müller A. Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations. Chemistry - a European Journal. 2007;13(27):7650-7658.
Merca, A., Haupt, E. T. K., Mitra, T., Bögge, H., Rehder, D., & Müller, A. (2007). Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations. Chemistry - a European Journal, 13(27), 7650-7658. https://doi.org/10.1002/chem.200700294
Merca, Alice, Haupt, Erhard T. K., Mitra, Tamoghna, Bögge, Hartmut, Rehder, Dieter, and Müller, Achim. 2007. “Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations”. Chemistry - a European Journal 13 (27): 7650-7658.
Merca, A., Haupt, E. T. K., Mitra, T., Bögge, H., Rehder, D., and Müller, A. (2007). Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations. Chemistry - a European Journal 13, 7650-7658.
Merca, A., et al., 2007. Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations. Chemistry - a European Journal, 13(27), p 7650-7658.
A. Merca, et al., “Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations”, Chemistry - a European Journal, vol. 13, 2007, pp. 7650-7658.
Merca, A., Haupt, E.T.K., Mitra, T., Bögge, H., Rehder, D., Müller, A.: Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations. Chemistry - a European Journal. 13, 7650-7658 (2007).
Merca, Alice, Haupt, Erhard T. K., Mitra, Tamoghna, Bögge, Hartmut, Rehder, Dieter, and Müller, Achim. “Mimicking biological cation-transport based on sphere-surface supramolecular chemistry: Simultaneous interaction of porous capsules with molecular plugs and passing cations”. Chemistry - a European Journal 13.27 (2007): 7650-7658.
9 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Incorporation of Keplerate-type Mo-O based macroanions into Zn2Al-LDH results in the formation of all-inorganic composite films with remarkable third-order optical nonlinearity.
Ren H, Shehzad FK, Zhou Y, Zhang L, Iqbal A, Long Y., Dalton Trans 47(17), 2018
PMID: 29671437
Ren H, Shehzad FK, Zhou Y, Zhang L, Iqbal A, Long Y., Dalton Trans 47(17), 2018
PMID: 29671437
Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo132 } Capsule System.
Garai S, Bögge H, Merca A, Petina OA, Grego A, Gouzerh P, Haupt ET, Weinstock IA, Müller A., Angew Chem Int Ed Engl 55(23), 2016
PMID: 27140207
Garai S, Bögge H, Merca A, Petina OA, Grego A, Gouzerh P, Haupt ET, Weinstock IA, Müller A., Angew Chem Int Ed Engl 55(23), 2016
PMID: 27140207
Tunable Keplerate Type-Cluster "Mo132 " Cavity with Dicarboxylate Anions.
Lai TL, Awada M, Floquet S, Roch-Marchal C, Watfa N, Marrot J, Haouas M, Taulelle F, Cadot E., Chemistry 21(38), 2015
PMID: 26224211
Lai TL, Awada M, Floquet S, Roch-Marchal C, Watfa N, Marrot J, Haouas M, Taulelle F, Cadot E., Chemistry 21(38), 2015
PMID: 26224211
Tracking "apolar" NMe4+ ions within two polyoxothiomolybdates that have the same pores: smaller clathrate and larger highly porous clusters in action.
Korenev VS, Boulay AG, Haouas M, Bannani F, Fedin VP, Sokolov MN, Terazzi E, Garai S, Müller A, Taulelle F, Marrot J, Leclerc N, Floquet S, Cadot E., Chemistry 20(11), 2014
PMID: 24519761
Korenev VS, Boulay AG, Haouas M, Bannani F, Fedin VP, Sokolov MN, Terazzi E, Garai S, Müller A, Taulelle F, Marrot J, Leclerc N, Floquet S, Cadot E., Chemistry 20(11), 2014
PMID: 24519761
Capsules with highly active pores and interiors: versatile platforms at the nanoscale.
Müller A, Gouzerh P., Chemistry 20(17), 2014
PMID: 24644235
Müller A, Gouzerh P., Chemistry 20(17), 2014
PMID: 24644235
Solid-state dynamics of uranyl polyoxometalates.
Alam TM, Liao Z, Zakharov LN, Nyman M., Chemistry 20(27), 2014
PMID: 24889825
Alam TM, Liao Z, Zakharov LN, Nyman M., Chemistry 20(27), 2014
PMID: 24889825
Guests on different internal capsule sites exchange with each other and with the outside.
Petina O, Rehder D, Haupt ET, Grego A, Weinstock IA, Merca A, Bögge H, Szakács J, Müller A., Angew Chem Int Ed Engl 50(2), 2011
PMID: 21132826
Petina O, Rehder D, Haupt ET, Grego A, Weinstock IA, Merca A, Bögge H, Szakács J, Müller A., Angew Chem Int Ed Engl 50(2), 2011
PMID: 21132826
Hydrophobic interactions and clustering in a porous capsule: option to remove hydrophobic materials from water.
Schäffer C, Todea AM, Bögge H, Petina OA, Rehder D, Haupt ET, Müller A., Chemistry 17(35), 2011
PMID: 21748814
Schäffer C, Todea AM, Bögge H, Petina OA, Rehder D, Haupt ET, Müller A., Chemistry 17(35), 2011
PMID: 21748814
Confinement and step-wise reopening of channels in an artificial cell/inorganic capsule: a 7Li NMR study.
Haupt ET, Wontorra C, Rehder D, Merca A, Müller A., Chemistry 14(29), 2008
PMID: 18773407
Haupt ET, Wontorra C, Rehder D, Merca A, Müller A., Chemistry 14(29), 2008
PMID: 18773407
52 References
Daten bereitgestellt von Europe PubMed Central.
AUTHOR UNKNOWN, 2002
AUTHOR UNKNOWN, 1996
Cronin, 2004
Long, Chem. Eur. J. 12(), 2006
Hall, Chem. Commun. (), 2003
Cronin, Angew. Chem. 118(), 2006
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 45(), 2006
Gouzerh, Actual. Chim. 298(), 2006
Müller, Chem. Commun. (), 1999
Müller, Coord. Chem. Rev. 245(), 2003
Cronin, 2003
Müller, Inorg. Synth. 34(), 2004
Müller, 2004
Müller, Angew. Chem. 118(), 2006
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 45(), 2006
Polyoxometalate clusters, nanostructures and materials: from self assembly to designer materials and devices.
Long DL, Burkholder E, Cronin L., Chem Soc Rev 36(1), 2006
PMID: 17173149
Long DL, Burkholder E, Cronin L., Chem Soc Rev 36(1), 2006
PMID: 17173149
Müller, Angew. Chem. 116(), 2004
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 43(), 2004
Gross, Chem. World 1(), 2004
Müller, Angew. Chem. 116(), 2004
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 43(), 2004
Haupt, Chem. Commun. (), 2005
Countercation transport modeled by porous spherical molybdenum oxide based nanocapsules.
Rehder D, Haupt ET, Bogge H, Muller A., Chem Asian J 1(1-2), 2006
PMID: 17441040
Rehder D, Haupt ET, Bogge H, Muller A., Chem Asian J 1(1-2), 2006
PMID: 17441040
Müller, Angew. Chem. 114(), 2002
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 41(), 2002
Müller, Angew. Chem. 115(), 2003
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 42(), 2003
Müller, C. R. Chim. 8(), 2005
Henry, J. Mol. Liq. 118(), 2005
Müller, Angew. Chem. 115(), 2003
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 42(), 2003
Müller, Angew. Chem. 117(), 2005
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 44(), 2005
Alberts, 2002
AUTHOR UNKNOWN, 2004
MacKinnon, Angew. Chem. 116(), 2004
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 43(), 2004
Red blood cell sodium-lithium countertransport and risk of future hypertension: the Olivetti Prospective Heart Study.
Strazzullo P, Siani A, Cappuccio FP, Trevisan M, Ragone E, Russo L, Iacone R, Farinaro E., Hypertension 31(6), 1998
PMID: 9622143
Strazzullo P, Siani A, Cappuccio FP, Trevisan M, Ragone E, Russo L, Iacone R, Farinaro E., Hypertension 31(6), 1998
PMID: 9622143
AUTHOR UNKNOWN, 2006
Nelson, 2005
AUTHOR UNKNOWN, 0
Toward complex matter: supramolecular chemistry and self-organization.
Lehn JM., Proc. Natl. Acad. Sci. U.S.A. 99(8), 2002
PMID: 11929970
Lehn JM., Proc. Natl. Acad. Sci. U.S.A. 99(8), 2002
PMID: 11929970
Deprotonations and charges of well-defined {Mo72Fe30} nanoacids simply stepwise tuned by pH allow control/variation of related self-assembly processes.
Liu T, Imber B, Diemann E, Liu G, Cokleski K, Li H, Chen Z, Muller A., J. Am. Chem. Soc. 128(49), 2006
PMID: 17147404
Liu T, Imber B, Diemann E, Liu G, Cokleski K, Li H, Chen Z, Muller A., J. Am. Chem. Soc. 128(49), 2006
PMID: 17147404
A complete macroion-"blackberry" assembly-macroion transition with continuously adjustable assembly sizes in {Mo132} water/acetone systems.
Kistler ML, Bhatt A, Liu G, Casa D, Liu T., J. Am. Chem. Soc. 129(20), 2007
PMID: 17465544
Kistler ML, Bhatt A, Liu G, Casa D, Liu T., J. Am. Chem. Soc. 129(20), 2007
PMID: 17465544
Brown, 1981
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 0
Is competition between Li+ and Mg2+ the underlying theme in the proposed mechanisms for the pharmacological action of lithium salts in bipolar disorder?
Mota de Freitas D, Castro MM, Geraldes CF., Acc. Chem. Res. 39(4), 2006
PMID: 16618096
Mota de Freitas D, Castro MM, Geraldes CF., Acc. Chem. Res. 39(4), 2006
PMID: 16618096
Liu, J. Cluster Sci. 17(), 2006
Ion selectivity in a semisynthetic K+ channel locked in the conductive conformation.
Valiyaveetil FI, Leonetti M, Muir TW, Mackinnon R., Science 314(5801), 2006
PMID: 17095703
Valiyaveetil FI, Leonetti M, Muir TW, Mackinnon R., Science 314(5801), 2006
PMID: 17095703
Atkins, 2002
Harris, Pure Appl. Chem. 73(), 2001
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Quellen
PMID: 17639541
PubMed | Europe PMC
Suchen in
Google Scholar