A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames
Hansen N, Klippenstein SJ, Westmoreland Phillip R, Kasper T, Kohse-Höinghaus K, Wang J, Cool TA (2008)
PHYSICAL CHEMISTRY CHEMICAL PHYSICS 10(3): 366-374.
Zeitschriftenaufsatz
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Autor*in
Hansen, Nils;
Klippenstein, Stephen J.;
Westmoreland, P.hillip R.;
Kasper, Tina;
Kohse-Höinghaus, KatharinaUniBi;
Wang, Juan;
Cool, Terrill A.
Einrichtung
Abstract / Bemerkung
Polyynic structures in fuel-rich low-pressure flames are observed using VUV photoionization molecular-beam mass spectrometry. High-level ab initio calculations of ionization energies for C2nH2 (n = 1-5) and partially hydrogenated CnH4 (n = 7-8) polyynes are compared with photoionization e. ciency measurements in flames fuelled by allene, propyne, and cyclopentene. C2nH2 (n = 1-5) intermediates are unambiguously identified, while HC C-C C-CH = C = CH2, HC C-C C-C C-CH = CH2 (vinyltriacetylene) and HC C-C C-CH = CH-C CH are likely to contribute to the C7H4 and C8H4 signals. Mole fraction pro. les as a function of distance from the burner are presented. C7H4 and C8H4 isomers are likely to be formed by reactions of C2H and C4H radicals but other plausible formation pathways are also discussed. Heats of formation and ionization energies of several combustion intermediates have been determined for the first time.
Erscheinungsjahr
2008
Zeitschriftentitel
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Band
10
Ausgabe
3
Seite(n)
366-374
ISSN
1463-9076
eISSN
1463-9084
Page URI
https://pub.uni-bielefeld.de/record/1630836
Zitieren
Hansen N, Klippenstein SJ, Westmoreland Phillip R, et al. A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames. PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 2008;10(3):366-374.
Hansen, N., Klippenstein, S. J., Westmoreland, Phillip R., Kasper, T., Kohse-Höinghaus, K., Wang, J., & Cool, T. A. (2008). A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 10(3), 366-374. https://doi.org/10.1039/b711578d
Hansen, Nils, Klippenstein, Stephen J., Westmoreland, P.hillip R., Kasper, Tina, Kohse-Höinghaus, Katharina, Wang, Juan, and Cool, Terrill A. 2008. “A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames”. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 10 (3): 366-374.
Hansen, N., Klippenstein, S. J., Westmoreland, Phillip R., Kasper, T., Kohse-Höinghaus, K., Wang, J., and Cool, T. A. (2008). A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 10, 366-374.
Hansen, N., et al., 2008. A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 10(3), p 366-374.
N. Hansen, et al., “A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames”, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 10, 2008, pp. 366-374.
Hansen, N., Klippenstein, S.J., Westmoreland, Phillip R., Kasper, T., Kohse-Höinghaus, K., Wang, J., Cool, T.A.: A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames. PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 10, 366-374 (2008).
Hansen, Nils, Klippenstein, Stephen J., Westmoreland, P.hillip R., Kasper, Tina, Kohse-Höinghaus, Katharina, Wang, Juan, and Cool, Terrill A. “A combined ab initio and photoionization mass spectrometric study of polyynes in fuel-rich flames”. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 10.3 (2008): 366-374.
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