Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles)

Weber L (2008)
Coordination Chemistry Reviews 252(1-2): 1-31.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
1,3,2-Diazaborolines(2,3-dihydro-1H-1,3,2-diazaboroles) are compounds at the interface between inorganic, organometallic and organic chemistry. The planar rings with 6 pi-electrons may be regarded as heteroarenes, as evident by NMR and photoelectron spectra and confirmed by quantum chemical studies. High-yield syntheses of functionalized 1,3,2-diazaborolines have been elaborated, providing a prolific area of chemistry. Conjugation of the vacant 2p(z)-orbital on the boron center with the pi* orbital of attached organic pi-systems proved to be responsible for unique absorption and emission characteristics of 1,3,2-diazaborolinyl functionalized biphenyls, thiophenes and dithiophenes. Most of the functionalized diazaborolines show clean irreversible oxidation waves in their cyclovoltammograms. (C) 2007 Elsevier B.V. All rights reserved.
Stichworte
structures; heteroarenes; diazaborolines; luminescence
Erscheinungsjahr
2008
Zeitschriftentitel
Coordination Chemistry Reviews
Band
252
Ausgabe
1-2
Seite(n)
1-31
ISSN
0010-8545
Page URI
https://pub.uni-bielefeld.de/record/1630774

Zitieren

Weber L. Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews. 2008;252(1-2):1-31.
Weber, L. (2008). Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews, 252(1-2), 1-31. https://doi.org/10.1016/j.ccr.2007.02.014
Weber, L. (2008). Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews 252, 1-31.
Weber, L., 2008. Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews, 252(1-2), p 1-31.
L. Weber, “Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles)”, Coordination Chemistry Reviews, vol. 252, 2008, pp. 1-31.
Weber, L.: Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles). Coordination Chemistry Reviews. 252, 1-31 (2008).
Weber, Lothar. “Recent developments in the chemistry of 1,3,2-diazaborolines-(2,3-dihydro-1H-1,3,2-diazaboroles)”. Coordination Chemistry Reviews 252.1-2 (2008): 1-31.

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