Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III)

Müller A, Diemann E, Krickemeyer E, Bögge H, Menke C, Kuhlmann C (1996)
MONATSHEFTE FUR CHEMIE 127(1): 43-49.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The structure and packing of the lattice of the compounds (PPh(4))(3)[As(CS3)(3)] (1), (PPh(4))(3)[Bi(CS3)(3)] (2), and (PPh(4))(3)[Fe(CS3)(3)]. H2O (3) is discussed in terms of hostguest chemistry in a ''soft'' matrix of large cations. The hitherto unknown Fe-complex was characterized by elemental analysis and single crystal structure analysis. Here CS32- acts as a classical bidentate ligand, whereas in the case of the arsenic and bismut complexes, the coordination of this ligand is essentially unidentate due to an interaction with the lone pair on the central atom. For the last two complexes, there seems to be an influence of the packing on the coordination geometry.
Stichworte
trithiocarbonato complexes; chemistry; host-guest; tetraphenylphosphonium salts
Erscheinungsjahr
1996
Zeitschriftentitel
MONATSHEFTE FUR CHEMIE
Band
127
Ausgabe
1
Seite(n)
43-49
ISSN
0026-9247
eISSN
1434-4475
Page URI
https://pub.uni-bielefeld.de/record/1628990

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Müller A, Diemann E, Krickemeyer E, Bögge H, Menke C, Kuhlmann C. Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE. 1996;127(1):43-49.
Müller, A., Diemann, E., Krickemeyer, E., Bögge, H., Menke, C., & Kuhlmann, C. (1996). Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE, 127(1), 43-49. doi:10.1007/BF00807407
Müller, A., Diemann, E., Krickemeyer, E., Bögge, H., Menke, C., and Kuhlmann, C. (1996). Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE 127, 43-49.
Müller, A., et al., 1996. Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE, 127(1), p 43-49.
A. Müller, et al., “Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III)”, MONATSHEFTE FUR CHEMIE, vol. 127, 1996, pp. 43-49.
Müller, A., Diemann, E., Krickemeyer, E., Bögge, H., Menke, C., Kuhlmann, C.: Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III). MONATSHEFTE FUR CHEMIE. 127, 43-49 (1996).
Müller, Achim, Diemann, Ekkehard, Krickemeyer, Erich, Bögge, Hartmut, Menke, C, and Kuhlmann, Christoph. “Remarkable host-guest relationships in tetraphenylphosphonium salts of tris-trithiocarbonato complexes of As(III),Bi(III), and Fe(III)”. MONATSHEFTE FUR CHEMIE 127.1 (1996): 43-49.