Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes
Kuck D, Audier HE (1997)
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE 324(11): 717-724.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Kuck, DietmarUniBi;
Audier, H. E.
Abstract / Bemerkung
The gas-phase reactions of C6H5CH2X and C6H5CH2CH2X (X = OH or halogen) with benzene in the presence of H3O+ lead to protonated diphenylalkanes. Prior to dissociation, the product ions formed by reaction with C6D6 undergo H/D exchange, which has been nsed to characterize their structure. Thus, the reaction of C6H5CH2CH2X yields selectively protonated 1,2-diphenylethane. This apparent selectivity is a consequence of the very short lifetime of the isomeric protonated 1,1-diphenylethane generated by reaction ofthe C6H5CHCH3+ ion by an SN1 mechanism.
Erscheinungsjahr
1997
Zeitschriftentitel
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE
Band
324
Ausgabe
11
Seite(n)
717-724
ISSN
1251-8069
Page URI
https://pub.uni-bielefeld.de/record/1627356
Zitieren
Kuck D, Audier HE. Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE. 1997;324(11):717-724.
Kuck, D., & Audier, H. E. (1997). Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE, 324(11), 717-724. https://doi.org/10.1016/S1251-8069(97)83177-6
Kuck, Dietmar, and Audier, H. E. 1997. “Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes”. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE 324 (11): 717-724.
Kuck, D., and Audier, H. E. (1997). Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE 324, 717-724.
Kuck, D., & Audier, H.E., 1997. Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE, 324(11), p 717-724.
D. Kuck and H.E. Audier, “Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes”, COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE, vol. 324, 1997, pp. 717-724.
Kuck, D., Audier, H.E.: Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE. 324, 717-724 (1997).
Kuck, Dietmar, and Audier, H. E. “Preparation and characterization of diphenylalkanes in the gas phase. Separation of isomeric products by their lifetimes”. COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE 324.11 (1997): 717-724.
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Suchen in
Google Scholar