On the electronic structure of dihalogenophosphenium cations
Schoeller W (1998)
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM 422(1-3): 285-291.
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Einrichtung
Abstract / Bemerkung
The bonding properties of the dihalogenophosphenium cations, PX2(+), X = F, Cl, Br, I, are evaluated by relativistic effective core potential calculations with a DZP basis set. Our investigations include an analysis of the singlet-triplet energy separation in the cations and the determination of the relative cation and anion stabilities in the gas phase, via corresponding group transfer reactions. A comparison is made with other stabilized, previously reported low-coordinated pi-bonded phosphorus cations. (C) 1998 Elsevier Science B.V.
Stichworte
singlet-triplet energy separation;
dihalogenophosphenium cations
Erscheinungsjahr
1998
Zeitschriftentitel
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM
Band
422
Ausgabe
1-3
Seite(n)
285-291
ISSN
0166-1280
Page URI
https://pub.uni-bielefeld.de/record/1626419
Zitieren
Schoeller W. On the electronic structure of dihalogenophosphenium cations. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM. 1998;422(1-3):285-291.
Schoeller, W. (1998). On the electronic structure of dihalogenophosphenium cations. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 422(1-3), 285-291. https://doi.org/10.1016/S0166-1280(97)00108-5
Schoeller, Wolfgang. 1998. “On the electronic structure of dihalogenophosphenium cations”. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM 422 (1-3): 285-291.
Schoeller, W. (1998). On the electronic structure of dihalogenophosphenium cations. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM 422, 285-291.
Schoeller, W., 1998. On the electronic structure of dihalogenophosphenium cations. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 422(1-3), p 285-291.
W. Schoeller, “On the electronic structure of dihalogenophosphenium cations”, JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, vol. 422, 1998, pp. 285-291.
Schoeller, W.: On the electronic structure of dihalogenophosphenium cations. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM. 422, 285-291 (1998).
Schoeller, Wolfgang. “On the electronic structure of dihalogenophosphenium cations”. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM 422.1-3 (1998): 285-291.
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