Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds

Canac, Y; Bourissou, D; Baceiredo, A; Gornitzka, H; Schoeller, Wolfgang; Bertrand, G

Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds

Canac Y, Bourissou D, Baceiredo A, Gornitzka H, Schoeller W, Bertrand G (1998)
SCIENCE 279(5359): 2080-2082.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

Download

Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!

DOI

https://doi.org/10.1126/science.279.5359.2080

Autor*in

Canac, Y; Bourissou, D; Baceiredo, A; Gornitzka, H; Schoeller, Wolfgang^UniBi; Bertrand, G

Einrichtung

Fakultät für Chemie > Theoretische Chemie

Abstract / Bemerkung

A tetraphosphabenzene analog of the postulated anti-tricyclohexylene, a singlet biradical valence isomer of benzene, has been isolated. The tricyclic derivative features one-electron phosphorus-phosphorus bonds, which result from the pi*-pi* interaction between two diphosphirenyl radicals. Such one-electron bonds may play a wider role in phosphorus chemistry.

Erscheinungsjahr

1998

Zeitschriftentitel

SCIENCE

Band

279

Ausgabe

5359

Seite(n)

2080-2082

ISSN

0036-8075

eISSN

1095-9203

Page URI

https://pub.uni-bielefeld.de/record/1626181

Zitieren

Canac Y, Bourissou D, Baceiredo A, Gornitzka H, Schoeller W, Bertrand G. Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE. 1998;279(5359):2080-2082.

Canac, Y., Bourissou, D., Baceiredo, A., Gornitzka, H., Schoeller, W., & Bertrand, G. (1998). Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE, 279(5359), 2080-2082. https://doi.org/10.1126/science.279.5359.2080

Canac, Y, Bourissou, D, Baceiredo, A, Gornitzka, H, Schoeller, Wolfgang, and Bertrand, G. 1998. “Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds”. SCIENCE 279 (5359): 2080-2082.

Canac, Y., Bourissou, D., Baceiredo, A., Gornitzka, H., Schoeller, W., and Bertrand, G. (1998). Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE 279, 2080-2082.

Canac, Y., et al., 1998. Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE, 279(5359), p 2080-2082.

Y. Canac, et al., “Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds”, SCIENCE, vol. 279, 1998, pp. 2080-2082.

Canac, Y., Bourissou, D., Baceiredo, A., Gornitzka, H., Schoeller, W., Bertrand, G.: Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds. SCIENCE. 279, 2080-2082 (1998).

Canac, Y, Bourissou, D, Baceiredo, A, Gornitzka, H, Schoeller, Wolfgang, and Bertrand, G. “Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus bonds”. SCIENCE 279.5359 (1998): 2080-2082.

Daten bereitgestellt von European Bioinformatics Institute (EBI)

14 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

One-Electron Bonds in Frustrated Lewis Pair TPB Ligands: Boron Behaving as a Lewis Base.
Kusevska E, Montero-Campillo MM, Mó O, Yáñez M., Angew Chem Int Ed Engl 56(24), 2017
PMID: 28488324

A very peculiar family of N-heterocyclic phosphines: unusual structures and the unique reactivity of 1,3,2-diazaphospholenes.
Gudat D., Dalton Trans 45(14), 2016
PMID: 26863391

Boron-Boron One-Electron Sigma Bonds versus B-X-B Bridged Structures.
Kusevska E, Montero-Campillo MM, Mó O, Yáñez M., Chemistry 22(38), 2016
PMID: 27530734

1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres.
Wu D, Kong L, Li Y, Ganguly R, Kinjo R., Nat Commun 6(), 2015
PMID: 26073993

Confirmed by X-ray crystallography: the B⋅B one-electron σ bond.
Hübner A, Diehl AM, Diefenbach M, Endeward B, Bolte M, Lerner HW, Holthausen MC, Wagner M., Angew Chem Int Ed Engl 53(19), 2014
PMID: 24668861

Isolation and reversible dimerization of a selenium-selenium three-electron σ-bond.
Zhang S, Wang X, Su Y, Qiu Y, Zhang Z, Wang X., Nat Commun 5(), 2014
PMID: 24916712

Low-valent Ge(2) and Ge(4) species trapped by N-heterocyclic gallylene.
Doddi A, Gemel C, Winter M, Fischer RA, Goedecke C, Rzepa HS, Frenking G., Angew Chem Int Ed Engl 52(1), 2013
PMID: 23169591

Silicon-containing formal 4π-electron four-membered ring systems: antiaromatic, aromatic, or nonaromatic?
Yang YF, Cheng GJ, Zhu J, Zhang X, Inoue S, Wu YD., Chemistry 18(24), 2012
PMID: 22532432

Planarity takes over in the C(x)H(x)P(6-x) (x = 0-6) series at x = 4.
Galeev TR, Boldyrev AI., Phys Chem Chem Phys 13(46), 2011
PMID: 21869975

Towards spontaneous heterolysis of the homonuclear P-P bond in diphosphines: the case of diazaphospholeniumtriphospholides.
Benko Z, Burck S, Gudat D, Hofmann M, Lissner F, Nyulászi L, Zenneck U., Chemistry 16(9), 2010
PMID: 20099287

Tetraphosphabenzenes obtained via a triphosphacyclobutadiene intermediate.
Piro NA, Cummins CC., Angew Chem Int Ed Engl 48(5), 2009
PMID: 19101967

Eta3-diphosphavinylcarbene: a P2 analogue of the Dötz intermediate.
Aktas H, Slootweg JC, Ehlers AW, Lutz M, Spek AL, Lammertsma K., Angew Chem Int Ed Engl 48(17), 2009
PMID: 19072973

New adventures in the molecular chemistry of phosphorus.
Russell CA., Angew Chem Int Ed Engl 48(27), 2009
PMID: 19441029

Dimerization of a cyclo-1sigma4,3sigma2,4sigma2-triphosphapentadienyl radical: evidence for phosphorus-phosphorus odd-electron bonds.
Kato T, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G., Angew Chem Int Ed Engl 44(34), 2005
PMID: 16052642