The electronic structure of the tris(diaminophosphanyl)carbenium ion. A quantum chemical investigation

Schoeller W, Tubbesing U (1998)
INORGANIC CHEMISTRY 37(13): 3183-3185.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
contrast to the triaminomethyl carbenium ion which adopts a planar structure, a diaminophosphanyl substituent attached at the electron-deficient carbenium center introduces anionic character. As a consequence the tris(diaminophosphanyl)carbenium ion possesses an unusual equilibrium structure with three different PC bond lengths. The bonding situation is rationalized in the framework of contributing donor-acceptor structures to the overall bonding. A similar bonding situation is obtained for the phosphanyl substituent attached to an electron-deficient center.
Erscheinungsjahr
Zeitschriftentitel
INORGANIC CHEMISTRY
Band
37
Ausgabe
13
Seite(n)
3183-3185
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Schoeller W, Tubbesing U. The electronic structure of the tris(diaminophosphanyl)carbenium ion. A quantum chemical investigation. INORGANIC CHEMISTRY. 1998;37(13):3183-3185.
Schoeller, W., & Tubbesing, U. (1998). The electronic structure of the tris(diaminophosphanyl)carbenium ion. A quantum chemical investigation. INORGANIC CHEMISTRY, 37(13), 3183-3185. doi:10.1021/ic9701524
Schoeller, W., and Tubbesing, U. (1998). The electronic structure of the tris(diaminophosphanyl)carbenium ion. A quantum chemical investigation. INORGANIC CHEMISTRY 37, 3183-3185.
Schoeller, W., & Tubbesing, U., 1998. The electronic structure of the tris(diaminophosphanyl)carbenium ion. A quantum chemical investigation. INORGANIC CHEMISTRY, 37(13), p 3183-3185.
W. Schoeller and U. Tubbesing, “The electronic structure of the tris(diaminophosphanyl)carbenium ion. A quantum chemical investigation”, INORGANIC CHEMISTRY, vol. 37, 1998, pp. 3183-3185.
Schoeller, W., Tubbesing, U.: The electronic structure of the tris(diaminophosphanyl)carbenium ion. A quantum chemical investigation. INORGANIC CHEMISTRY. 37, 3183-3185 (1998).
Schoeller, Wolfgang, and Tubbesing, U. “The electronic structure of the tris(diaminophosphanyl)carbenium ion. A quantum chemical investigation”. INORGANIC CHEMISTRY 37.13 (1998): 3183-3185.