From simple building blocks to structures with increasing size and complexity
Müller A, Kögerler P (1999)
COORDINATION CHEMISTRY REVIEWS 182(1): 3-17.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Müller, AchimUniBi
;
Kögerler, Paul
![](https://pub.uni-bielefeld.de/images/icon_orcid.png)
Einrichtung
Abstract / Bemerkung
In Nature, complex molecular systems like proteins have evolved (natura naturans) which are perfectly suited to their functions. These are produced in a sequence of steps under dissipative conditions-that is, far from equilibrium. The challenge for the chemist is to nsynthesize correspondingly complex multi-functional molecules also under non-equilibrium (non-dissipative) conditions using multi-component, one-pot reactions, without having to separate and purify each single intermediate product. Relevant model reactions have been discovered in solutions of simple oxoanions of the early transition metals: novel types of molecular growth processes with feedback (including a type of induced cascade) are described leading to different ring-shaped, electron-rich, mixed-valence, giant polyoxomolybdates with nanosized cavities. These can-due to the generation of defects-be covalently linked together to form chains as well as layered mesoporous compounds with properties relevant for materials science. They can also start growing again. The largest polyoxometalate cluster obtained on the basis of this growth process to-date has 248 Mo atoms. Remarkably, such giant ring species can also act as hosts for other clusters forming new types of supramolecular compounds. (C) 1999 Elsevier Science S.A. All rights reserved.
Erscheinungsjahr
1999
Zeitschriftentitel
COORDINATION CHEMISTRY REVIEWS
Band
182
Ausgabe
1
Seite(n)
3-17
ISSN
0010-8545
Page URI
https://pub.uni-bielefeld.de/record/1623484
Zitieren
Müller A, Kögerler P. From simple building blocks to structures with increasing size and complexity. COORDINATION CHEMISTRY REVIEWS. 1999;182(1):3-17.
Müller, A., & Kögerler, P. (1999). From simple building blocks to structures with increasing size and complexity. COORDINATION CHEMISTRY REVIEWS, 182(1), 3-17. https://doi.org/10.1016/S0010-8545(98)00226-4
Müller, Achim, and Kögerler, Paul. 1999. “From simple building blocks to structures with increasing size and complexity”. COORDINATION CHEMISTRY REVIEWS 182 (1): 3-17.
Müller, A., and Kögerler, P. (1999). From simple building blocks to structures with increasing size and complexity. COORDINATION CHEMISTRY REVIEWS 182, 3-17.
Müller, A., & Kögerler, P., 1999. From simple building blocks to structures with increasing size and complexity. COORDINATION CHEMISTRY REVIEWS, 182(1), p 3-17.
A. Müller and P. Kögerler, “From simple building blocks to structures with increasing size and complexity”, COORDINATION CHEMISTRY REVIEWS, vol. 182, 1999, pp. 3-17.
Müller, A., Kögerler, P.: From simple building blocks to structures with increasing size and complexity. COORDINATION CHEMISTRY REVIEWS. 182, 3-17 (1999).
Müller, Achim, and Kögerler, Paul. “From simple building blocks to structures with increasing size and complexity”. COORDINATION CHEMISTRY REVIEWS 182.1 (1999): 3-17.
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Suchen in