On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]
Weber L, Scheffer MH, Stammler H-G, Neumann B (1999)
Inorganica Chimica Acta 291(1-2): 311-316.
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Abstract / Bemerkung
Reacting metallophosphaalkene [(eta(5)-C5Me5)(CO)(2)FeP=C(NMe2)(2)] (1) with [(eta(5)-C5H5)Rh(CO)(2)] affords the condensation product [C5Me4CH=C(NMe2)PH{Rh(CO)(C5H5)}Fe(CO)(2)] (8). In contrast to this, the eta(2)-dimetallodiarsene rhodium complex [eta(2)-{(eta(5)-C5Me5)(CO)(2)Fe-As=As-Fe(CO)(2)(eta(5)-C5Me5)}Rh(C5H5)( CO)] (9) is formed from the metalloarsaalkene [(eta(5)-C5Me5)(CO)(2)FeAs=C(NMe2)(2)] (6) and [(eta(5)-C5H5)Rh(CO)(2)]. The novel compounds are characterized by elemental analyses, spectroscopic data (IR, H-1, C-13, P-31 NMR, MS) and by a single crystal X-ray analysis of 8. (C) 1999 Elsevier Science S.A. All rights reserved.
Stichworte
iron complexes;
phosphaalkene complexes;
arsaalkene;
crystal structures;
complexes
Erscheinungsjahr
1999
Zeitschriftentitel
Inorganica Chimica Acta
Band
291
Ausgabe
1-2
Seite(n)
311-316
ISSN
0020-1693
Page URI
https://pub.uni-bielefeld.de/record/1622313
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Weber L, Scheffer MH, Stammler H-G, Neumann B. On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]. Inorganica Chimica Acta. 1999;291(1-2):311-316.
Weber, L., Scheffer, M. H., Stammler, H. - G., & Neumann, B. (1999). On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]. Inorganica Chimica Acta, 291(1-2), 311-316. https://doi.org/10.1016/S0020-1693(99)00131-0
Weber, Lothar, Scheffer, Matthias H., Stammler, Hans-Georg, and Neumann, Beate. 1999. “On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]”. Inorganica Chimica Acta 291 (1-2): 311-316.
Weber, L., Scheffer, M. H., Stammler, H. - G., and Neumann, B. (1999). On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]. Inorganica Chimica Acta 291, 311-316.
Weber, L., et al., 1999. On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]. Inorganica Chimica Acta, 291(1-2), p 311-316.
L. Weber, et al., “On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]”, Inorganica Chimica Acta, vol. 291, 1999, pp. 311-316.
Weber, L., Scheffer, M.H., Stammler, H.-G., Neumann, B.: On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]. Inorganica Chimica Acta. 291, 311-316 (1999).
Weber, Lothar, Scheffer, Matthias H., Stammler, Hans-Georg, and Neumann, Beate. “On the contrasting reactivity of the phosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] and the arsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] towards [(η5-C5H5Rh(CO)2]”. Inorganica Chimica Acta 291.1-2 (1999): 311-316.
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