Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry
Müller A, Koop M, Bögge H, Schmidtmann M, Peters F, Kögerler P (1999)
CHEMICAL COMMUNICATIONS (18): 1885-1886.
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Abstract / Bemerkung
The unique polyoxometalate compound Na-20[{(MoO3)-O-VI- (H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3)}(10)({Mo-VI - O-2(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)]. xH(2)O 1 (x approximate to 170) shows remarkable structural features: e.g. (i) {Mo-VI/Mo-5(VI)}-type pentagons as building blocks (being present in the relevant reaction medium as disposition), (ii) a 'magnetic ring-shaped band' built up by ten linked {V-3(IV)} triangles having common corners and (iii) two {NaSO4}(5) rings encapsulated inside the cavity of an icosidodecahedron formed by twenty triangular and twelve pentagonal faces built up by ten Mo-VI and twenty V-IV centres, respectively.
Erscheinungsjahr
1999
Zeitschriftentitel
CHEMICAL COMMUNICATIONS
Ausgabe
18
Seite(n)
1885-1886
ISSN
1359-7345
eISSN
1364-548X
Page URI
https://pub.uni-bielefeld.de/record/1622052
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Müller A, Koop M, Bögge H, Schmidtmann M, Peters F, Kögerler P. Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry. CHEMICAL COMMUNICATIONS. 1999;(18):1885-1886.
Müller, A., Koop, M., Bögge, H., Schmidtmann, M., Peters, F., & Kögerler, P. (1999). Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry. CHEMICAL COMMUNICATIONS(18), 1885-1886. https://doi.org/10.1039/a904724g
Müller, Achim, Koop, M, Bögge, Hartmut, Schmidtmann, Marc, Peters, F, and Kögerler, Paul. 1999. “Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry”. CHEMICAL COMMUNICATIONS, no. 18: 1885-1886.
Müller, A., Koop, M., Bögge, H., Schmidtmann, M., Peters, F., and Kögerler, P. (1999). Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry. CHEMICAL COMMUNICATIONS, 1885-1886.
Müller, A., et al., 1999. Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry. CHEMICAL COMMUNICATIONS, (18), p 1885-1886.
A. Müller, et al., “Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry”, CHEMICAL COMMUNICATIONS, 1999, pp. 1885-1886.
Müller, A., Koop, M., Bögge, H., Schmidtmann, M., Peters, F., Kögerler, P.: Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry. CHEMICAL COMMUNICATIONS. 1885-1886 (1999).
Müller, Achim, Koop, M, Bögge, Hartmut, Schmidtmann, Marc, Peters, F, and Kögerler, Paul. “Building blocks as disposition in solution: [{(MoO3)-O-VI(H2O)}(10){(VO)-O-IV(H2O)}(20){(Mo-VI/(Mo5O21)-O-VI)(H2O)(3 )}(10)({(MoO2)-O-VI(H2O)(2)}(5/2))(2) ({NaSO4}(5))(2)](20-), a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry”. CHEMICAL COMMUNICATIONS 18 (1999): 1885-1886.
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