Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium
Weber L, Scheffer MH, Stammler H-G, Stammler A (1999)
European Journal of Inorganic Chemistry (9): 1607-1611.
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Abstract / Bemerkung
Reaction of equimolar amounts of the ferriophosphaalkene [(eta(5)-C5Me5)(CO)(2)FeP=C(NMe2)(2)] (1a) or the ferrioarsaalkene [(eta(5)-C5Me5)(CO)(2)FeAs=C(NMe2)(2)] (1b) with trimethylaluminium, trimethylgallium and trimethylindium afforded the adducts [(eta(5)-C5Me5)(CO)(2)FeE{MMe3}C(NMe2)(2)] with E = P; M = Al (2a), Ga (3a), In (4a) and E = As; M = Al (2b), Ga (3b), and In (4b). These compounds feature eta(1)-coordination of the phosphaalkene or the arsaalkene ligand towards the Lewis acid via the pnictogen atom. The molecular structures of 2a and 3a were elucidated by X-ray diffraction analyses.
Stichworte
arsaalkenes;
phosphaalkenes;
gallium;
indium;
aluminium
Erscheinungsjahr
1999
Zeitschriftentitel
European Journal of Inorganic Chemistry
Ausgabe
9
Seite(n)
1607-1611
ISSN
1434-1948
Page URI
https://pub.uni-bielefeld.de/record/1621457
Zitieren
Weber L, Scheffer MH, Stammler H-G, Stammler A. Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium. European Journal of Inorganic Chemistry. 1999;(9):1607-1611.
Weber, L., Scheffer, M. H., Stammler, H. - G., & Stammler, A. (1999). Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium. European Journal of Inorganic Chemistry(9), 1607-1611.
Weber, Lothar, Scheffer, Matthias H., Stammler, Hans-Georg, and Stammler, Anja. 1999. “Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium”. European Journal of Inorganic Chemistry, no. 9: 1607-1611.
Weber, L., Scheffer, M. H., Stammler, H. - G., and Stammler, A. (1999). Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium. European Journal of Inorganic Chemistry, 1607-1611.
Weber, L., et al., 1999. Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium. European Journal of Inorganic Chemistry, (9), p 1607-1611.
L. Weber, et al., “Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium”, European Journal of Inorganic Chemistry, 1999, pp. 1607-1611.
Weber, L., Scheffer, M.H., Stammler, H.-G., Stammler, A.: Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium. European Journal of Inorganic Chemistry. 1607-1611 (1999).
Weber, Lothar, Scheffer, Matthias H., Stammler, Hans-Georg, and Stammler, Anja. “Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe-P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2FeAs=C(NMe2)2] Towards Tromethylaluminium, -gallium and -indium”. European Journal of Inorganic Chemistry 9 (1999): 1607-1611.
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