Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH
Müller A, Beugholt C, Koop M, Das SK, Schmidtmann M, Bögge H (1999)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625(12): 1960-1962.
Zeitschriftenaufsatz
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Autor*in
Müller, AchimUniBi 
;
Beugholt, Christian;
Koop, M;
Das, Samar K.;
Schmidtmann, Marc;
Bögge, HartmutUniBi
;
Beugholt, Christian;
Koop, M;
Das, Samar K.;
Schmidtmann, Marc;
Bögge, HartmutUniBiEinrichtung
Abstract / Bemerkung
The syntheses and structures of the two mixed-valence crystalline molybdenum blue compounds Na-26[Mo142O432(H2O)(58)H-14] ca. 300H(2)O (1) (containing the maximal number of well defined defects which influence the overall structure and the reactivity of the anionic cluster) and Na-16[(MoO3)(176)(H2O)(63)(CH3OH)(17)H-16].ca. 600H(2)O ca. 6 CH3OH (2) (obtained in an optimized high-yield synthesis) are reported with reference to the critical conditions required for the isolation of corresponding crystalline materials.
Stichworte
molybdenum blue;
inorganic rings;
mixed-valence compound;
polyoxometallate;
defect structures;
cluster
Erscheinungsjahr
1999
Zeitschriftentitel
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Band
625
Ausgabe
12
Seite(n)
1960-1962
ISSN
0044-2313
eISSN
1521-3749
Page URI
https://pub.uni-bielefeld.de/record/1621001
Zitieren
Müller A, Beugholt C, Koop M, Das SK, Schmidtmann M, Bögge H. Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 1999;625(12):1960-1962.
Müller, A., Beugholt, C., Koop, M., Das, S. K., Schmidtmann, M., & Bögge, H. (1999). Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 625(12), 1960-1962. https://doi.org/10.1002/(SICI)1521-3749(199912)625:12<1960::AID-ZAAC1960>3.0.CO;2-A
Müller, Achim, Beugholt, Christian, Koop, M, Das, Samar K., Schmidtmann, Marc, and Bögge, Hartmut. 1999. “Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625 (12): 1960-1962.
Müller, A., Beugholt, C., Koop, M., Das, S. K., Schmidtmann, M., and Bögge, H. (1999). Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625, 1960-1962.
Müller, A., et al., 1999. Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 625(12), p 1960-1962.
A. Müller, et al., “Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 625, 1999, pp. 1960-1962.
Müller, A., Beugholt, C., Koop, M., Das, S.K., Schmidtmann, M., Bögge, H.: Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 625, 1960-1962 (1999).
Müller, Achim, Beugholt, Christian, Koop, M, Das, Samar K., Schmidtmann, Marc, and Bögge, Hartmut. “Facile and optimized syntheses and structures of crystalline molybdenum blue compounds including one with an interesting high degree of defects: Na-26[Mo142O432(H2O)(58)H-14] center dot ca. 300 H2O and Na-16[(Mo O-3)(176)(H2O)(63)(CH3OH)(17)H-16] center dot ca. 600 H2O center dot ca. 6 CH3OH”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 625.12 (1999): 1960-1962.
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