Pentacoordination at fluoro-substituted silanes by weak Lewis donor addition

Schoeller W, Rozhenko A (2000)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2): 375-381.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
Quantum chemical calculations at the ab initio level indicate that Lewis donors such as amine or water form weak donor-acceptor complexes with fluoro-substituted silanes. The strength of the donor-acceptor formation increases with increasing degree of fluorine substitution. Amine and water form strong adducts only for tetrafluorosilane. The higher element homologues of Lewis donors, such as phosphane and sulfur dihydride, do not in essence coordinate. A considerable role in donor-acceptor formation is exerted by chelation effects which impose intramolecular interactions on functionalized ligands. The corresponding structures are explored.
Stichworte
donor-acceptor systems; fluorine; ab initio calculations; silicon
Erscheinungsjahr
2000
Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Ausgabe
2
Seite(n)
375-381
ISSN
1434-1948
Page URI
https://pub.uni-bielefeld.de/record/1620774

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Schoeller W, Rozhenko A. Pentacoordination at fluoro-substituted silanes by weak Lewis donor addition. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2000;(2):375-381.
Schoeller, W., & Rozhenko, A. (2000). Pentacoordination at fluoro-substituted silanes by weak Lewis donor addition. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(2), 375-381.
Schoeller, W., and Rozhenko, A. (2000). Pentacoordination at fluoro-substituted silanes by weak Lewis donor addition. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 375-381.
Schoeller, W., & Rozhenko, A., 2000. Pentacoordination at fluoro-substituted silanes by weak Lewis donor addition. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (2), p 375-381.
W. Schoeller and A. Rozhenko, “Pentacoordination at fluoro-substituted silanes by weak Lewis donor addition”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, pp. 375-381.
Schoeller, W., Rozhenko, A.: Pentacoordination at fluoro-substituted silanes by weak Lewis donor addition. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 375-381 (2000).
Schoeller, Wolfgang, and Rozhenko, A. “Pentacoordination at fluoro-substituted silanes by weak Lewis donor addition”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2 (2000): 375-381.