Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes
Müller C, Jutzi P (2000)
Synthesis 2000(3): 389-394.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Müller, Christian;
Jutzi, PeterUniBi
Abstract / Bemerkung
[2-(N,N-Dialkylamino)ethy]cyclopentadienes have been used for the synthesis of the novel amino-functionalized silicon- and carbon-bridged cyclopentadiene derivatives 3a-c, 7, 10 and 13a-c. The C-C and C-Si coupling reactions described here are regioselective leading exclusively to the formation of 1,3-disubstituted isomers, as proven by H-1 NMR spectroscopy. The bis-cyclopentadienes 3a-c, 7, 10 and 13a-c can be deprotonated to the corresponding dianionic species.
Stichworte
amino-functionalized cyclopentadienes;
fulvenes;
ansa-metallocenes;
regioselectivity
Erscheinungsjahr
2000
Zeitschriftentitel
Synthesis
Band
2000
Ausgabe
3
Seite(n)
389-394
ISSN
0039-7881
Page URI
https://pub.uni-bielefeld.de/record/1620449
Zitieren
Müller C, Jutzi P. Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis. 2000;2000(3):389-394.
Müller, C., & Jutzi, P. (2000). Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis, 2000(3), 389-394. https://doi.org/10.1055/s-2000-6341
Müller, Christian, and Jutzi, Peter. 2000. “Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes”. Synthesis 2000 (3): 389-394.
Müller, C., and Jutzi, P. (2000). Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis 2000, 389-394.
Müller, C., & Jutzi, P., 2000. Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis, 2000(3), p 389-394.
C. Müller and P. Jutzi, “Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes”, Synthesis, vol. 2000, 2000, pp. 389-394.
Müller, C., Jutzi, P.: Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes. Synthesis. 2000, 389-394 (2000).
Müller, Christian, and Jutzi, Peter. “Regioselective synthesis of carbon- and silicon-bridged 2-(N,N-Dialkylamino)ethyl-substituted cyclopentadienes”. Synthesis 2000.3 (2000): 389-394.
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