Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-)
Jutzi P, Müller C, Stammler A, Stammler H-G (2000)
Organometallics 19(7): 1442-1444.
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Abstract / Bemerkung
The reaction of LiB(C6F5)(4) with HCl in diethyl ether afforded the new oxonium acid [H(OEt2)2](+)-[B(C6F5)(4)](-) (1) as a colorless crystalline solid, which was characterized by NMR spectroscopy, by elemental analysis, and by single-crystal X-ray diffraction. The application of 1 is demonstrated in the generation of the complex: {[eta(5)-C5H3(CH2CH2NMe2)CMe2-eta(5)-C13H8]ZrCH3}(+)- [B(C6F5)(4)](-) (3) containing an intramolecularly donor-stabilized alkylzirconocene cation.
Erscheinungsjahr
2000
Zeitschriftentitel
Organometallics
Band
19
Ausgabe
7
Seite(n)
1442-1444
ISSN
0276-7333
eISSN
1520-6041
Page URI
https://pub.uni-bielefeld.de/record/1620173
Zitieren
Jutzi P, Müller C, Stammler A, Stammler H-G. Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-). Organometallics. 2000;19(7):1442-1444.
Jutzi, P., Müller, C., Stammler, A., & Stammler, H. - G. (2000). Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-). Organometallics, 19(7), 1442-1444. https://doi.org/10.1021/om990612w
Jutzi, Peter, Müller, Christian, Stammler, Anja, and Stammler, Hans-Georg. 2000. “Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-)”. Organometallics 19 (7): 1442-1444.
Jutzi, P., Müller, C., Stammler, A., and Stammler, H. - G. (2000). Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-). Organometallics 19, 1442-1444.
Jutzi, P., et al., 2000. Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-). Organometallics, 19(7), p 1442-1444.
P. Jutzi, et al., “Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-)”, Organometallics, vol. 19, 2000, pp. 1442-1444.
Jutzi, P., Müller, C., Stammler, A., Stammler, H.-G.: Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-). Organometallics. 19, 1442-1444 (2000).
Jutzi, Peter, Müller, Christian, Stammler, Anja, and Stammler, Hans-Georg. “Synthesis, crystal structure, and application of the oxonium acid [H(OEt2)(2)](+)[B(C6F5)(4)](-)”. Organometallics 19.7 (2000): 1442-1444.
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