Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex

Chiorescu I, Wernsdorfer W, Müller A, Bögge H, Barbara B (2000)
PHYSICAL REVIEW LETTERS 84(15): 3454-3457.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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DOI
Autor*in
Chiorescu, I; Wernsdorfer, W; Müller, AchimUniBi ; Bögge, HartmutUniBi; Barbara, B
Einrichtung
Fakultät für Chemie > Anorganische Chemie I
Abstract / Bemerkung
Time resolved magnetization measurements have been performed on a spin 1/2 molecular complex, so-called V-15. Despite the absence of a barrier, magnetic hysteresis is observed over a time scale of several seconds. A detailed analysis in terms of a dissipative two-level model is given, in which fluctuations and splittings are of the same energy. Spin-phonon coupling leads to long relaxation times and to a particular "butterfly" hysteresis loop.
Erscheinungsjahr
2000
Zeitschriftentitel
PHYSICAL REVIEW LETTERS
Band
84
Ausgabe
15
Seite(n)
3454-3457
ISSN
0031-9007
eISSN
1079-7114
Page URI
https://pub.uni-bielefeld.de/record/1620140

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Chiorescu I, Wernsdorfer W, Müller A, Bögge H, Barbara B. Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex. PHYSICAL REVIEW LETTERS. 2000;84(15):3454-3457.
Chiorescu, I., Wernsdorfer, W., Müller, A., Bögge, H., & Barbara, B. (2000). Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex. PHYSICAL REVIEW LETTERS, 84(15), 3454-3457. https://doi.org/10.1103/PhysRevLett.84.3454
Chiorescu, I, Wernsdorfer, W, Müller, Achim, Bögge, Hartmut, and Barbara, B. 2000. “Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex”. PHYSICAL REVIEW LETTERS 84 (15): 3454-3457.
Chiorescu, I., Wernsdorfer, W., Müller, A., Bögge, H., and Barbara, B. (2000). Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex. PHYSICAL REVIEW LETTERS 84, 3454-3457.
Chiorescu, I., et al., 2000. Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex. PHYSICAL REVIEW LETTERS, 84(15), p 3454-3457.
I. Chiorescu, et al., “Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex”, PHYSICAL REVIEW LETTERS, vol. 84, 2000, pp. 3454-3457.
Chiorescu, I., Wernsdorfer, W., Müller, A., Bögge, H., Barbara, B.: Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex. PHYSICAL REVIEW LETTERS. 84, 3454-3457 (2000).
Chiorescu, I, Wernsdorfer, W, Müller, Achim, Bögge, Hartmut, and Barbara, B. “Butterfly hysteresis loop and dissipative spin reversal in the S = 1/2, V-15 molecular complex”. PHYSICAL REVIEW LETTERS 84.15 (2000): 3454-3457.

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Krylov DS, Liu F, Brandenburg A, Spree L, Bon V, Kaskel S, Wolter AUB, Büchner B, Avdoshenko SM, Popov AA., Phys Chem Chem Phys 20(17), 2018
PMID: 29671443
Slow magnetic relaxation in a dimeric Mn2Ca2 complex enabled by the large Mn(iii) rhombicity.
Arauzo A, Bartolomé E, Benniston AC, Melnic S, Shova S, Luzón J, Alonso PJ, Barra AL, Bartolomé J., Dalton Trans 46(3), 2017
PMID: 27990520
Slow Magnetic Relaxation in a Mononuclear Ruthenium(III) Complex.
Wu SQ, Miyazaki Y, Nakano M, Su SQ, Yao ZS, Kou HZ, Sato O., Chemistry 23(42), 2017
PMID: 28618082
A Low Spin Manganese(IV) Nitride Single Molecule Magnet.
Ding M, Cutsail GE, Aravena D, Amoza M, Rouzières M, Dechambenoit P, Losovyj Y, Pink M, Ruiz E, Clérac R, Smith JM., Chem Sci 7(9), 2016
PMID: 27746891
Giant spin-phonon bottleneck effects in evaporable vanadyl-based molecules with long spin coherence.
Tesi L, Lunghi A, Atzori M, Lucaccini E, Sorace L, Totti F, Sessoli R., Dalton Trans 45(42), 2016
PMID: 27484897
Studies on the Magnetic Ground State of a Spin Möbius Strip.
Newton GN, Hoshino N, Matsumoto T, Shiga T, Nakano M, Nojiri H, Wernsdorfer W, Furukawa Y, Oshio H., Chemistry 22(40), 2016
PMID: 27546317
Spin-orbit coupled molecular quantum magnetism realized in inorganic solid.
Park SY, Do SH, Choi KY, Kang JH, Jang D, Schmidt B, Brando M, Kim BH, Kim DH, Butch NP, Lee S, Park JH, Ji S., Nat Commun 7(), 2016
PMID: 27650796
Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2.
Feng X, Liu JL, Pedersen KS, Nehrkorn J, Schnegg A, Holldack K, Bendix J, Sigrist M, Mutka H, Samohvalov D, Aguilà D, Tong ML, Long JR, Clérac R., Chem Commun (Camb) 52(87), 2016
PMID: 27739552
Semimetal-functionalised polyoxovanadates.
Monakhov KY, Bensch W, Kögerler P., Chem Soc Rev 44(23), 2015
PMID: 26344788
A C2-symmetric antimonato polyoxovanadate cluster [V16Sb4O42(H2O)](8-) derived from the {V18O42} archetype.
Antonova E, Näther C, Kögerler P, Bensch W., Dalton Trans 41(23), 2012
PMID: 22495299
Controlling nucleation and crystal growth of a distinct polyoxovanadate cluster: an in situ energy dispersive X-ray diffraction study under solvothermal conditions.
Antonova E, Seidlhofer B, Wang J, Hinz M, Bensch W., Chemistry 18(48), 2012
PMID: 23055444
Chromium(III) stars and butterflies: synthesis, structural and magnetic studies of tetrametallic clusters.
Batchelor LJ, Sander M, Tuna F, Helliwell M, Moro F, van Slageren J, Burzurí E, Montero O, Evangelisti M, Luis F, McInnes EJ., Dalton Trans 40(19), 2011
PMID: 21465040
Structure-related frustrated magnetism of nanosized polyoxometalates: aesthetics and properties in harmony.
Kögerler P, Tsukerblat B, Müller A., Dalton Trans (1), 2010
PMID: 20023927
A molecular magnet confined in the nanocage of a globular protein.
Mitra RK, Verma PK, Wulferding D, Menzel D, Mitra T, Todea AM, Lemmens P, Müller A, Pal SK., Chemphyschem 11(2), 2010
PMID: 20024976
Comparison among various expressions of complex admittance for quantum systems in contact with a heat reservoir.
Saeki M, Uchiyama C, Mori T, Miyashita S., Phys Rev E Stat Nonlin Soft Matter Phys 81(3 pt 1), 2010
PMID: 20365721
Broadband electron spin resonance at 4-40 GHz and magnetic fields up to 10 T.
Schlegel C, Dressel M, van Slageren J., Rev Sci Instrum 81(9), 2010
PMID: 20886988
Master equation approach to line shape in dissipative systems.
Uchiyama C, Aihara M, Saeki M, Miyashita S., Phys Rev E Stat Nonlin Soft Matter Phys 80(2 pt 1), 2009
PMID: 19792098
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Lopez N, Prosvirin AV, Zhao H, Wernsdorfer W, Dunbar KR., Chemistry 15(42), 2009
PMID: 19760709
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Bertaina S, Gambarelli S, Mitra T, Tsukerblat B, Müller A, Barbara B., Nature 453(7192), 2008
PMID: 18464738
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Trif M, Troiani F, Stepanenko D, Loss D., Phys Rev Lett 101(21), 2008
PMID: 19113446
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Sañudo EC, Muryn CA, Helliwell MA, Timco GA, Wernsdorfer W, Winpenny RE., Chem Commun (Camb) (8), 2007
PMID: 17308636
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Jönsson PE, Mathieu R, Wernsdorfer W, Tkachuk AM, Barbara B., Phys Rev Lett 98(25), 2007
PMID: 17678041
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Kiebach R, Näther C, Kögerler P, Bensch W., Dalton Trans (30), 2007
PMID: 17893765
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Zhang YZ, Wernsdorfer W, Pan F, Wang ZM, Gao S., Chem Commun (Camb) (31), 2006
PMID: 16883417
Low temperature EPR spectra of the mesoscopic cluster V15: the role of antisymmetric exchange.
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PMID: 16942248
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Tolis EI, Engelhardt LP, Mason PV, Rajaraman G, Kindo K, Luban M, Matsuo A, Nojiri H, Raftery J, Schröder C, Timco GA, Tuna F, Wernsdorfer W, Winpenny RE., Chemistry 12(35), 2006
PMID: 17009372
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Rousochatzakis I, Ajiro Y, Mitamura H, Kögerler P, Luban M., Phys Rev Lett 94(14), 2005
PMID: 15904102
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PMID: 12484964
Hamiltonian of the V15 spin system from first-principles density-functional calculations.
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PMID: 11327980
Nuclear spin driven quantum relaxation in LiY0.998Ho0.002F4.
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PMID: 11082657

26 References

Daten bereitgestellt von Europe PubMed Central.


Thomas, Nature (London) 383(), 1996
Macroscopic measurement of resonant magnetization tunneling in high-spin molecules.
Friedman JR, Sarachik MP, Tejada J, Ziolo R., Phys. Rev. Lett. 76(20), 1996
PMID: 10061120

Barbara, J. Magn. Magn. Mater. 200(), 1999

Barbara, Phys. World 12(), 1999

Prokof'ev, Phys. Rev. Lett. 80(), 1998

Hartmann-Boutron, Int. J. Mod. Phys. B 10(), 1996

Leuenberger, Europhys. Lett. 46(), 1999

Belessa, Phys. Rev. Lett. 83(), 1999

Müller, Angew. Chem., Int. Ed. Engl. 27(), 1991

Gatteschi, Mol. Eng. 3(), 1993

Gatteschi, Nature (London) 354(), 1991

Leggett, Rev. Mod. Phys. 59(), 1987

Grifoni, Phys. Rep. 304(), 1998

Zener, Proc. R. Soc. London, Ser. A 137(), 1932

Landau, Phys. Z. Sowjetunion 2(), 1932

De, Phys. Rev. B 56(), 1997

Miyashita, J. Phys. Soc. Jpn. 64(), 1995

Kayanuma, Phys. Rev. B 57(), 1998
Dephasing of interference in Landau-Zener transitions.
Shimshoni E, Stern A., Phys. Rev., B Condens. Matter 47(15), 1993
PMID: 10005017

Wernsdorfer, Phys. Rev. Lett. 79(), 1997

Katsnelson, Phys. Rev. B 59(), 1999

Barbara, J. Magn. Magn. Mater. 177–181(), 1998

Carter, 1977

Van, Phys. Rev. 59(), 1941

Stevens, Rep. Prog. Phys. 30(), 1967

Abragam, 1970
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