The gas-phase basicities of 6-methylfulvene and 6,6-dimethylfulvene as determined by the thermokinetic method

Mormann M, Salpin J-Y, Kuck D (1999)
EUROPEAN MASS SPECTROMETRY 5(1): 441-447.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Mormann, Michael; Salpin, Jean-Yves; Kuck, DietmarUniBi
Abstract / Bemerkung
The gas-phase basicities (GB) of 6-methylfulvene and 6,6-dimethylfulvene have been determined by Fourier transform ion cyclotron resonance spectrometry using the thermokinetic method. Proton affinities (PA) and heats of formation derived from the GB values reveal the relatively high thermochemical stability of fulvenium ions which, in line with the previous studies on the parent C6H6 species, is only c, 40-50 kJ mol(-1) less than those of the most stable protonated forms of the isomeric alkylbenzenes.
Stichworte
fulvenes; fulvenium ions; thermokinetic method; proton affinities; basicities; protonated fulvene derivatives; gas-phase
Erscheinungsjahr
1999
Zeitschriftentitel
EUROPEAN MASS SPECTROMETRY
Band
5
Ausgabe
1
Seite(n)
441-447
ISSN
1356-1049
Page URI
https://pub.uni-bielefeld.de/record/1619689

Zitieren

Mormann M, Salpin J-Y, Kuck D. The gas-phase basicities of 6-methylfulvene and 6,6-dimethylfulvene as determined by the thermokinetic method. EUROPEAN MASS SPECTROMETRY. 1999;5(1):441-447.
Mormann, M., Salpin, J. - Y., & Kuck, D. (1999). The gas-phase basicities of 6-methylfulvene and 6,6-dimethylfulvene as determined by the thermokinetic method. EUROPEAN MASS SPECTROMETRY, 5(1), 441-447. doi:10.1255/ejms.307
Mormann, M., Salpin, J. - Y., and Kuck, D. (1999). The gas-phase basicities of 6-methylfulvene and 6,6-dimethylfulvene as determined by the thermokinetic method. EUROPEAN MASS SPECTROMETRY 5, 441-447.
Mormann, M., Salpin, J.-Y., & Kuck, D., 1999. The gas-phase basicities of 6-methylfulvene and 6,6-dimethylfulvene as determined by the thermokinetic method. EUROPEAN MASS SPECTROMETRY, 5(1), p 441-447.
M. Mormann, J.-Y. Salpin, and D. Kuck, “The gas-phase basicities of 6-methylfulvene and 6,6-dimethylfulvene as determined by the thermokinetic method”, EUROPEAN MASS SPECTROMETRY, vol. 5, 1999, pp. 441-447.
Mormann, M., Salpin, J.-Y., Kuck, D.: The gas-phase basicities of 6-methylfulvene and 6,6-dimethylfulvene as determined by the thermokinetic method. EUROPEAN MASS SPECTROMETRY. 5, 441-447 (1999).
Mormann, Michael, Salpin, Jean-Yves, and Kuck, Dietmar. “The gas-phase basicities of 6-methylfulvene and 6,6-dimethylfulvene as determined by the thermokinetic method”. EUROPEAN MASS SPECTROMETRY 5.1 (1999): 441-447.

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