Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface

Müller, Achim; Beugholt, Christian; Bögge, Hartmut; Schmidtmann, Marc

Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface

Müller A, Beugholt C, Bögge H, Schmidtmann M (2000)
INORGANIC CHEMISTRY 39(15): 3112-3113.

Zeitschriftenaufsatz | Veröffentlicht | Englisch

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DOI

https://doi.org/10.1021/ic000168l

Autor*in

Müller, Achim^UniBi ; Beugholt, Christian; Bögge, Hartmut^UniBi; Schmidtmann, Marc

Einrichtung

Fakultät für Chemie > Anorganische Chemie I

Abstract / Bemerkung

A new type of giant-wheel-shaped anion (see title) is obtained during the formation of the "classical" tetradecameric molybdenum-blue-type species [{Mo-2){Mo-8}{Mo-1}](14) in the presence of Pr3+. The Pr3+ cations substitute {Mo-2} units and thereby increase the curvature of each ring, which leads to destruction and smaller ring sizes.

Erscheinungsjahr

2000

Zeitschriftentitel

INORGANIC CHEMISTRY

Band

Ausgabe

Seite(n)

3112-3113

ISSN

0020-1669

eISSN

1520-510X

Page URI

https://pub.uni-bielefeld.de/record/1619381

Zitieren

Müller A, Beugholt C, Bögge H, Schmidtmann M. Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY. 2000;39(15):3112-3113.

Müller, A., Beugholt, C., Bögge, H., & Schmidtmann, M. (2000). Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY, 39(15), 3112-3113. https://doi.org/10.1021/ic000168l

Müller, Achim, Beugholt, Christian, Bögge, Hartmut, and Schmidtmann, Marc. 2000. “Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface”. INORGANIC CHEMISTRY 39 (15): 3112-3113.

Müller, A., Beugholt, C., Bögge, H., and Schmidtmann, M. (2000). Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY 39, 3112-3113.

Müller, A., et al., 2000. Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY, 39(15), p 3112-3113.

A. Müller, et al., “Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface”, INORGANIC CHEMISTRY, vol. 39, 2000, pp. 3112-3113.

Müller, A., Beugholt, C., Bögge, H., Schmidtmann, M.: Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface. INORGANIC CHEMISTRY. 39, 3112-3113 (2000).

Müller, Achim, Beugholt, Christian, Bögge, Hartmut, and Schmidtmann, Marc. “Influencing the size of giant rings by manipulating their curvatures: Na-6[Mo120O366(H2O)(48)H-12{Pr(H2O)(5)}(6)]center dot(similar to 200H(2)O) with open shell metal centers at the cluster surface”. INORGANIC CHEMISTRY 39.15 (2000): 3112-3113.

Daten bereitgestellt von European Bioinformatics Institute (EBI)

13 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Exploring the Molecular Growth of Two Gigantic Half-Closed Polyoxometalate Clusters {Mo180 } and {Mo130 Ce6 }.
Xuan W, Pow R, Long DL, Cronin L., Angew Chem Int Ed Engl 56(33), 2017
PMID: 28508585

Human versus Robots in the Discovery and Crystallization of Gigantic Polyoxometalates.
Duros V, Grizou J, Xuan W, Hosni Z, Long DL, Miras HN, Cronin L., Angew Chem Int Ed Engl 56(36), 2017
PMID: 28649740

Homologous size-extension of hybrid vanadate capsules - solid state structures, solution stability and surface deposition.
Mahimaidoss MB, Krasnikov SA, Reck L, Onet CI, Breen JM, Zhu N, Marzec B, Shvets IV, Schmitt W., Chem Commun (Camb) 50(18), 2014
PMID: 24435072

An unusual fan-type polyanion with a silver cation located at the axial center, [AgAsIII2(AsIIIAsVMo4O18(OH)2)3]11-.
Ma Y, Xue Q, Min S, Zhang Y, Hu H, Gao S, Xue G., Dalton Trans 42(10), 2013
PMID: 23258499

From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry.
Müller A, Gouzerh P., Chem Soc Rev 41(22), 2012
PMID: 22948798

Chemical adaptability: the integration of different kinds of matter into giant molecular metal oxides.
Müller A, Merca A, Al-Karawi AJ, Garai S, Bögge H, Hou G, Wu L, Haupt ET, Rehder D, Haso F, Liu T., Chemistry 18(51), 2012
PMID: 23180718

Synthesis, characterisation and cytotoxicity of polyoxometalate/carboxymethyl chitosan nanocomposites.
Geisberger G, Paulus S, Carraro M, Bonchio M, Patzke GR., Chemistry 17(16), 2011
PMID: 21322072

A nanosized molybdenum oxide wheel with a unique electronic-necklace structure: STM study with submolecular resolution.
Zhong D, Sousa FL, Müller A, Chi L, Fuchs H., Angew Chem Int Ed Engl 50(31), 2011
PMID: 21717545

Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster.
Hashikawa A, Fujimoto M, Hayashi Y, Miyasaka H., Chem Commun (Camb) 47(45), 2011
PMID: 22012482

Polyoxotungstate-encapsulated Gd(6) and Yb(10) complexes.
Hussain F, Gable RW, Speldrich M, Kögerler P, Boskovic C., Chem Commun (Camb) (3), 2009
PMID: 19209318

Electronic control of spin coupling in keplerate-type polyoxomolybdates.
Botar B, Ellern A, Hermann R, Kögerler P., Angew Chem Int Ed Engl 48(48), 2009
PMID: 19859930

Caesium-templated lanthanoid-containing polyoxotungstates.
Hussain F, Spingler B, Conrad F, Speldrich M, Kögerler P, Boskovic C, Patzke GR., Dalton Trans (23), 2009
PMID: 19488435

Nanometer-sized molybdenum-iron oxide capsule-surface modifications: external and internal.
Müller A, Bögge H, Sousa FL, Schmidtmann M, Kurth DG, Volkmer D, van Slageren J, Dressel M, Kistler ML, Liu T., Small 3(6), 2007
PMID: 17385209