Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11)
Weber L, Pumpenmeier L, Stammler H-G, Neumann B (2000)
Journal of the Chemical Society. Dalton Transactions (23): 4379-4384.
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Abstract / Bemerkung
Insertion of one equivalent of methyl(phenyl)ketene or cyclohexyl(phenyl)ketene into the Sb-Si bond of [FeCp*(CO)(2){Sb(SiMe3)(2)}] afforded eta (1)-stibaallyliron complexes [(OC)(2)(eta (5)-C5Me5)Fe-Sb(SiMe3)C(OSiMe3)=(CRPh)-Ph-1] (R-1=c-C6H11 or Me). The remaining Sb-Si bond was readily cleaved by C2Cl6 to give complexes [(OC)(2)Cp*Fe-Sb(Cl)C(OSiMe3)=(CRPh)-Ph-1]. Treatment of the latter where R-1=Ph with LiSb(SiMe3)(2).2.8thf, LiC=CPh, or LiC(N-2)SiMe3 resulted in the formation of compounds [(OC)(2)Cp*Fe-Sb(R)C(OSiMe3)=CPh2 [R=Sb(SiMe3)(2), C=CPh or C(N-2)SiMe3]. The new compounds were characterized by elemental analyses and spectra (IR, H-1, C-13, Si-29 NMR). The molecular structure of [(OC)(2)Cp*Fe-Sb(Cl)C(OSiMe3)=CPh2] was elucidated by a single crystal X-ray diffraction analysis.
Erscheinungsjahr
2000
Zeitschriftentitel
Journal of the Chemical Society. Dalton Transactions
Ausgabe
23
Seite(n)
4379-4384
ISSN
1470-479X
eISSN
1364-5447
Page URI
https://pub.uni-bielefeld.de/record/1618469
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Weber L, Pumpenmeier L, Stammler H-G, Neumann B. Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11). Journal of the Chemical Society. Dalton Transactions. 2000;(23):4379-4384.
Weber, L., Pumpenmeier, L., Stammler, H. - G., & Neumann, B. (2000). Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11). Journal of the Chemical Society. Dalton Transactions(23), 4379-4384. https://doi.org/10.1039/b007366k
Weber, Lothar, Pumpenmeier, Lars, Stammler, Hans-Georg, and Neumann, Beate. 2000. “Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11)”. Journal of the Chemical Society. Dalton Transactions, no. 23: 4379-4384.
Weber, L., Pumpenmeier, L., Stammler, H. - G., and Neumann, B. (2000). Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11). Journal of the Chemical Society. Dalton Transactions, 4379-4384.
Weber, L., et al., 2000. Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11). Journal of the Chemical Society. Dalton Transactions, (23), p 4379-4384.
L. Weber, et al., “Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11)”, Journal of the Chemical Society. Dalton Transactions, 2000, pp. 4379-4384.
Weber, L., Pumpenmeier, L., Stammler, H.-G., Neumann, B.: Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11). Journal of the Chemical Society. Dalton Transactions. 4379-4384 (2000).
Weber, Lothar, Pumpenmeier, Lars, Stammler, Hans-Georg, and Neumann, Beate. “Synthesis, structure and reactivity of highly functionalized η1-stibaallyliron complexes [(η5-C5Me5)(CO)2Fe-Sb(Cl)C(OSiMe3)=CPhR (R = Ph, Me, c-C6H11)”. Journal of the Chemical Society. Dalton Transactions 23 (2000): 4379-4384.
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