A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes
Schmoldt P, Mattay J (2000)
JOURNAL OF INFORMATION RECORDING 25(1-2): 239-243.
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| Veröffentlicht | Englisch
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Autor*in
Schmoldt, P;
Mattay, JochenUniBi
Abstract / Bemerkung
Photoinduced electron transfer (PET) from triethylamine (TEA) to alpha -cyclopropyl ketones initiates a cyclopropylcarbinyl-homoallyl rearrangement. The resulting homoallyl radical can be used in cyclization reactions with unsaturated side chains present in the starting material. Thus a variety of bicyclic products is accessible depending on the position and length of the side chain. The synthesis of suitable alpha -cyclopropyl ketone precursors is achieved via oxa-di-pi -methane rearrangement.
Stichworte
reductive photoinduced electron transfer;
fragmentation cyclization reaction;
oxa-di-pi-methane rearrangement;
cyclopropyl ketones
Erscheinungsjahr
2000
Serien- oder Zeitschriftentitel
JOURNAL OF INFORMATION RECORDING
Band
25
Ausgabe
1-2
Seite(n)
239-243
ISSN
1025-6008
Page URI
https://pub.uni-bielefeld.de/record/1618200
Zitieren
Schmoldt P, Mattay J. A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING. 2000;25(1-2):239-243.
Schmoldt, P., & Mattay, J. (2000). A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING, 25(1-2), 239-243.
Schmoldt, P, and Mattay, Jochen. 2000. “A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes”, JOURNAL OF INFORMATION RECORDING, 25 (1-2): 239-243.
Schmoldt, P., and Mattay, J. (2000). A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING 25, 239-243.
Schmoldt, P., & Mattay, J., 2000. A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING, 25(1-2), p 239-243.
P. Schmoldt and J. Mattay, “A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes”, JOURNAL OF INFORMATION RECORDING, vol. 25, 2000, pp. 239-243.
Schmoldt, P., Mattay, J.: A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes. JOURNAL OF INFORMATION RECORDING. 25, 239-243 (2000).
Schmoldt, P, and Mattay, Jochen. “A convenient strategy to linear triquinane skeletons by photoinduced fragmentation-cyclization reactions of alpha-keto cyclopropanes”. JOURNAL OF INFORMATION RECORDING 25.1-2 (2000): 239-243.
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