PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions
Rinderhagen H, Grota J, Mattay J (2000)
JOURNAL OF INFORMATION RECORDING 25(1-2): 229-233.
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| Veröffentlicht | Englisch
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Autor*in
Rinderhagen, H;
Grota, J;
Mattay, JochenUniBi
Abstract / Bemerkung
Siloxy cyclopropanes are easily oxidizable by photoinduced electron transfer (PET) reagents. The fragmentation of the resulting radical cations leads to beta -ketoradicals. The usability of these radicals in intermolecular addition reactions is limited by polymerisation or reduction. This disadvantage can be partially circumvented by studying the influence of the concentration of the reaction partners.
Stichworte
radical addition reactions;
photoinduced electron transfer;
cyclopropanes
Erscheinungsjahr
2000
Serien- oder Zeitschriftentitel
JOURNAL OF INFORMATION RECORDING
Band
25
Ausgabe
1-2
Seite(n)
229-233
ISSN
1025-6008
Page URI
https://pub.uni-bielefeld.de/record/1618196
Zitieren
Rinderhagen H, Grota J, Mattay J. PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING. 2000;25(1-2):229-233.
Rinderhagen, H., Grota, J., & Mattay, J. (2000). PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING, 25(1-2), 229-233.
Rinderhagen, H, Grota, J, and Mattay, Jochen. 2000. “PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions”, JOURNAL OF INFORMATION RECORDING, 25 (1-2): 229-233.
Rinderhagen, H., Grota, J., and Mattay, J. (2000). PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING 25, 229-233.
Rinderhagen, H., Grota, J., & Mattay, J., 2000. PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING, 25(1-2), p 229-233.
H. Rinderhagen, J. Grota, and J. Mattay, “PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions”, JOURNAL OF INFORMATION RECORDING, vol. 25, 2000, pp. 229-233.
Rinderhagen, H., Grota, J., Mattay, J.: PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions. JOURNAL OF INFORMATION RECORDING. 25, 229-233 (2000).
Rinderhagen, H, Grota, J, and Mattay, Jochen. “PET-oxidative generation of beta-ketoradicals. Optimisation of intermolecular radical addition reactions”. JOURNAL OF INFORMATION RECORDING 25.1-2 (2000): 229-233.
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