Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds
Jutzi P, Keitemeyer S, Neumann B, Stammler A, Stammler H-G (2001)
ORGANOMETALLICS 20(1): 42-46.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Jutzi, PeterUniBi;
Keitemeyer, S;
Neumann, B;
Stammler, A;
Stammler, Hans-GeorgUniBi
Abstract / Bemerkung
GeCl(2)(.)dioxane reacts with 1 and 2 equiv of [2,4-di-tert-butyl-6-(tert-butoxymethyl)lithium (t-BomxLi) to give the germanium(II) compounds t-BomxGeCl(1) and [t-Bomx](2)Ge (2), respectively. Reaction with 2 equiv of [2,4-di-tert-butyl-6-(iso-propoxymethyl)phenyl]lithium (i-PomxLi) affords [i-Pomx](2)Ge (3). Compounds 1-3 show intramolecular coordination of the alkoxy ligand to the germanium(II) center. The use of the 2,4-di-tert-butyl-6(methoxymethyl)phenyl ligand (Momx) does not lead to the expected base-stabilized germanium(II) species Momx(2)Ge but gives the germanium(IV) compound MomxGe[OCH2(2,4-di-tert-butylphenyl)] (Me) (4) as the result of an intramolecular O-CH3 bond oxidative addition process; X-ray crystal structure determinations are presented for 1, 2, and 4.
Erscheinungsjahr
2001
Zeitschriftentitel
ORGANOMETALLICS
Band
20
Ausgabe
1
Seite(n)
42-46
ISSN
0276-7333
eISSN
1520-6041
Page URI
https://pub.uni-bielefeld.de/record/1618171
Zitieren
Jutzi P, Keitemeyer S, Neumann B, Stammler A, Stammler H-G. Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds. ORGANOMETALLICS. 2001;20(1):42-46.
Jutzi, P., Keitemeyer, S., Neumann, B., Stammler, A., & Stammler, H. - G. (2001). Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds. ORGANOMETALLICS, 20(1), 42-46. https://doi.org/10.1021/om000679f
Jutzi, Peter, Keitemeyer, S, Neumann, B, Stammler, A, and Stammler, Hans-Georg. 2001. “Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds”. ORGANOMETALLICS 20 (1): 42-46.
Jutzi, P., Keitemeyer, S., Neumann, B., Stammler, A., and Stammler, H. - G. (2001). Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds. ORGANOMETALLICS 20, 42-46.
Jutzi, P., et al., 2001. Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds. ORGANOMETALLICS, 20(1), p 42-46.
P. Jutzi, et al., “Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds”, ORGANOMETALLICS, vol. 20, 2001, pp. 42-46.
Jutzi, P., Keitemeyer, S., Neumann, B., Stammler, A., Stammler, H.-G.: Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds. ORGANOMETALLICS. 20, 42-46 (2001).
Jutzi, Peter, Keitemeyer, S, Neumann, B, Stammler, A, and Stammler, Hans-Georg. “Synthesis and structure of the first oxygen-donor-stabilized organogermanium(II) compounds”. ORGANOMETALLICS 20.1 (2001): 42-46.
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Suchen in
Google Scholar