A new type of calixarene: Octahydroxypyridine[4]arenes

Gerkensmeier T, Mattay J, Nather C (2001)
CHEMISTRY-A EUROPEAN JOURNAL 7(2): 465-474.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor/in
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Abstract / Bemerkung
A new type of calixarene has been synthesised. Like resorcinol and a number of resorcinol derivatives, 2,6-dihydroxypyridine has been proven to form cyclic tetramers in moderate yields with a number of aliphatic and two aromatic aldehydes in acidic media. The problem of the formation of configurational isomers can be reduced by increasing the reaction temperature and time. With electron-rich aromatic aldehydes, 2,6-dihydroxypyridine unexpectedly yields deep-coloured acyclic quinoid systems. The octahydroxypyridine[4]arenes may have a high potential as receptors for molecular recognition and self organisation.
Stichworte
supramolecular chemistry; molecular container; pyridines; calixarenes
Erscheinungsjahr
2001
Zeitschriftentitel
CHEMISTRY-A EUROPEAN JOURNAL
Band
7
Ausgabe
2
Seite(n)
465-474
ISSN
0947-6539
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/1618000

Zitieren

Gerkensmeier T, Mattay J, Nather C. A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL. 2001;7(2):465-474.
Gerkensmeier, T., Mattay, J., & Nather, C. (2001). A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL, 7(2), 465-474. doi:10.1002/1521-3765(20010119)7:2<465::AID-CHEM465>3.0.CO;2-A
Gerkensmeier, T., Mattay, J., and Nather, C. (2001). A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL 7, 465-474.
Gerkensmeier, T., Mattay, J., & Nather, C., 2001. A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL, 7(2), p 465-474.
T. Gerkensmeier, J. Mattay, and C. Nather, “A new type of calixarene: Octahydroxypyridine[4]arenes”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 7, 2001, pp. 465-474.
Gerkensmeier, T., Mattay, J., Nather, C.: A new type of calixarene: Octahydroxypyridine[4]arenes. CHEMISTRY-A EUROPEAN JOURNAL. 7, 465-474 (2001).
Gerkensmeier, T, Mattay, Jochen, and Nather, C. “A new type of calixarene: Octahydroxypyridine[4]arenes”. CHEMISTRY-A EUROPEAN JOURNAL 7.2 (2001): 465-474.

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