(NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies

Raab M, Sundermann A, Schick G, Loew A, Nieger M, Schoeller W, Niecke E (2001)
ORGANOMETALLICS 20(9): 1770-1775.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
DOI
Autor*in
Raab, M; Sundermann, A; Schick, G; Loew, A; Nieger, M; Schoeller, WolfgangUniBi; Niecke, E
Einrichtung
Fakultät für Chemie > Theoretische Chemie
Abstract / Bemerkung
Reactions of aminobis(diorganylamino)phosphanes (R2N)(2)PNH2 (R = iPr (a), Cy (b)) with Cp2MCl2 (M = Ti, Zr, Hf), CpTiCl3, and TiCl4 lead to the formation of the transition-metal complexes (R2N)(2)PN(H)MCp2Cp2Cl (M=Ti (1b), Zr (2a,b) Hf (3a,b)) (R2N)(2)P(H)NTiCpCl2 (8a,b), and (R2N)(2)P(H)NTiCl3 (10a,b), respectively. The influence of electronic effects of the metal fragment on the resulting equilibrium between the (NH)-phosphanylamido and the tautomeric (PH-iminophosphorane form is presented in detail.; Computational studies unambiguously confirm the experimental results. The molecular structures of 2a, 3a, and 8b have been determined by single-crystal S-ray diffraction.
Erscheinungsjahr
2001
Zeitschriftentitel
ORGANOMETALLICS
Band
20
Ausgabe
9
Seite(n)
1770-1775
ISSN
0276-7333
eISSN
1520-6041
Page URI
https://pub.uni-bielefeld.de/record/1617302

Zitieren

Raab M, Sundermann A, Schick G, et al. (NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies. ORGANOMETALLICS. 2001;20(9):1770-1775.
Raab, M., Sundermann, A., Schick, G., Loew, A., Nieger, M., Schoeller, W., & Niecke, E. (2001). (NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies. ORGANOMETALLICS, 20(9), 1770-1775. https://doi.org/10.1021/om000967b
Raab, M, Sundermann, A, Schick, G, Loew, A, Nieger, M, Schoeller, Wolfgang, and Niecke, E. 2001. “(NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies”. ORGANOMETALLICS 20 (9): 1770-1775.
Raab, M., Sundermann, A., Schick, G., Loew, A., Nieger, M., Schoeller, W., and Niecke, E. (2001). (NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies. ORGANOMETALLICS 20, 1770-1775.
Raab, M., et al., 2001. (NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies. ORGANOMETALLICS, 20(9), p 1770-1775.
M. Raab, et al., “(NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies”, ORGANOMETALLICS, vol. 20, 2001, pp. 1770-1775.
Raab, M., Sundermann, A., Schick, G., Loew, A., Nieger, M., Schoeller, W., Niecke, E.: (NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies. ORGANOMETALLICS. 20, 1770-1775 (2001).
Raab, M, Sundermann, A, Schick, G, Loew, A, Nieger, M, Schoeller, Wolfgang, and Niecke, E. “(NH)-phosphanylamido- and (PH)-phosphoraneiminato transition-metal complexes: Syntheses, structures, and computational studies”. ORGANOMETALLICS 20.9 (2001): 1770-1775.
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Suchen in

Google Scholar