Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties

Jutzi P, Müller C, Neumann B, Stammler H-G (2001)
European Journal of Inorganic Chemistry 625(2): 180-185.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
Donor substituted carbon- and silicon-bridged zirconocene dichlorides of the type [eta (5)-C13H8-CMe2-eta (5)-C5H3(CH2CH2NR2)]ZrCl2 (R = Me (2a), Et (2b), Pr-i (2c)) and [eta (5)-C13H8-SiMe2-eta (5)-C5H3(CH2CH2NR2)]ZrCl2 (R = Me (4a), Et (4b), Pr-i (4c)) have been prepared. Activation of 2a-c and 4a-c with excess methylalumoxane results in the formation of catalytically active species for the polymerization of ethylene and propylene. (C) 2001 Elsevier Science B.V. All rights reserved.
Stichworte
ansa-metallocenes; MAO; polymerization; zirconium; N-ligands
Erscheinungsjahr
2001
Zeitschriftentitel
European Journal of Inorganic Chemistry
Band
625
Ausgabe
2
Seite(n)
180-185
ISSN
0022-328X
Page URI
https://pub.uni-bielefeld.de/record/1617222

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Jutzi P, Müller C, Neumann B, Stammler H-G. Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry. 2001;625(2):180-185.
Jutzi, P., Müller, C., Neumann, B., & Stammler, H. - G. (2001). Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry, 625(2), 180-185. doi:10.1016/S0022-328X(01)00644-1
Jutzi, P., Müller, C., Neumann, B., and Stammler, H. - G. (2001). Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry 625, 180-185.
Jutzi, P., et al., 2001. Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry, 625(2), p 180-185.
P. Jutzi, et al., “Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties”, European Journal of Inorganic Chemistry, vol. 625, 2001, pp. 180-185.
Jutzi, P., Müller, C., Neumann, B., Stammler, H.-G.: Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties. European Journal of Inorganic Chemistry. 625, 180-185 (2001).
Jutzi, Peter, Müller, Christian, Neumann, Beate, and Stammler, Hans-Georg. “Dialkylaminoethyl-functionalized ansa-zirconocene dichlorides: synthesis, structure, and polymerization properties”. European Journal of Inorganic Chemistry 625.2 (2001): 180-185.