Classical and quantum magnetism in giant keplerate magnetic molecules

Müller A, Luban M, Schroder C, Modler R, Kögerler P, Axenovich M, Schnack J, Canfield PC, Bud'ko S, Harrison N (2001)
ChemPhysChem 2(8-9): 517-521.

Download
Es wurde kein Volltext hochgeladen. Nur Publikationsnachweis!
Zeitschriftenaufsatz | Veröffentlicht | Englisch
Autor
; ; ; ; ; ; ; ; ;
Abstract / Bemerkung
What might be effective for understanding the magnetism of emerging mesoscopic magnetic molecules? Three theoretical modelling methods successfully explain the experimental data on the largest paramagnet synthesized to date, the nano-sized Keplerate {Mo-VI(72) Fe-III(30)}. Surprisingly, this molecule follows the classical Heisenberg model even down to as low as 50 mK and its 30 spins exhibit highly symmetric order at low temperatures. Nearest-neighbor spin vectors (see picture) are canted by an external magnetic field while their projections maintain a frustration angle of 120 degrees.
Erscheinungsjahr
Zeitschriftentitel
ChemPhysChem
Band
2
Ausgabe
8-9
Seite(n)
517-521
ISSN
eISSN
PUB-ID

Zitieren

Müller A, Luban M, Schroder C, et al. Classical and quantum magnetism in giant keplerate magnetic molecules. ChemPhysChem. 2001;2(8-9):517-521.
Müller, A., Luban, M., Schroder, C., Modler, R., Kögerler, P., Axenovich, M., Schnack, J., et al. (2001). Classical and quantum magnetism in giant keplerate magnetic molecules. ChemPhysChem, 2(8-9), 517-521. doi:10.1002/1439-7641(20010917)2:8/9<517::AID-CPHC517>3.0.CO;2-1
Müller, A., Luban, M., Schroder, C., Modler, R., Kögerler, P., Axenovich, M., Schnack, J., Canfield, P. C., Bud'ko, S., and Harrison, N. (2001). Classical and quantum magnetism in giant keplerate magnetic molecules. ChemPhysChem 2, 517-521.
Müller, A., et al., 2001. Classical and quantum magnetism in giant keplerate magnetic molecules. ChemPhysChem, 2(8-9), p 517-521.
A. Müller, et al., “Classical and quantum magnetism in giant keplerate magnetic molecules”, ChemPhysChem, vol. 2, 2001, pp. 517-521.
Müller, A., Luban, M., Schroder, C., Modler, R., Kögerler, P., Axenovich, M., Schnack, J., Canfield, P.C., Bud'ko, S., Harrison, N.: Classical and quantum magnetism in giant keplerate magnetic molecules. ChemPhysChem. 2, 517-521 (2001).
Müller, Achim, Luban, M, Schroder, C, Modler, R, Kögerler, Paul, Axenovich, M, Schnack, Jürgen, Canfield, PC, Bud'ko, S, and Harrison, N. “Classical and quantum magnetism in giant keplerate magnetic molecules”. ChemPhysChem 2.8-9 (2001): 517-521.

43 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Copper Keplerates: High-Symmetry Magnetic Molecules.
Palacios MA, Moreno Pineda E, Sanz S, Inglis R, Pitak MB, Coles SJ, Evangelisti M, Nojiri H, Heesing C, Brechin EK, Schnack J, Winpenny RE., Chemphyschem 17(1), 2016
PMID: 26530901
Keplerate cluster (Mo-132) mediated electrostatic assembly of nanoparticles.
Gooch J, Jalan AA, Jones S, Hine CR, Alam R, Garai S, Maye MM, Müller A, Zubieta J., J Colloid Interface Sci 432(), 2014
PMID: 25086388
Electronic structure and soft-X-ray-induced photoreduction studies of iron-based magnetic polyoxometalates of type {(M)M5}12Fe(III)30 (M = Mo(VI), W(VI)).
Kuepper K, Derks C, Taubitz C, Prinz M, Joly L, Kappler JP, Postnikov A, Yang W, Kuznetsova TV, Wiedwald U, Ziemann P, Neumann M., Dalton Trans 42(22), 2013
PMID: 23403844
{Mo24Fe12} macrocycles: anion templation with large polyoxometalate guests.
Fang X, Hansen L, Haso F, Yin P, Pandey A, Engelhardt L, Slowing I, Li T, Liu T, Luban M, Johnston DC., Angew Chem Int Ed Engl 52(40), 2013
PMID: 23943611
Exploring the no-man's land between molecular nanomagnets and magnetic nanoparticles.
Gatteschi D, Fittipaldi M, Sangregorio C, Sorace L., Angew Chem Int Ed Engl 51(20), 2012
PMID: 22473984
Engineering polyoxometalates with emergent properties.
Miras HN, Yan J, Long DL, Cronin L., Chem Soc Rev 41(22), 2012
PMID: 22858601
Diversity in structures and properties of 3d-incorporating polyoxotungstates.
Oms O, Dolbecq A, Mialane P., Chem Soc Rev 41(22), 2012
PMID: 22890383
Large magnetocaloric effect in a Wells-Dawson type {Ni6Gd6P6} cage.
Zheng YZ, Evangelisti M, Winpenny RE., Angew Chem Int Ed Engl 50(16), 2011
PMID: 21442698
Reduced molybenum-oxide-based core-shell hybrids: "blue" electrons are delocalized on the shell.
Todea AM, Szakács J, Konar S, Bögge H, Crans DC, Glaser T, Rousselière H, Thouvenot R, Gouzerh P, Müller A., Chemistry 17(24), 2011
PMID: 21542032
Cubic assembly of a geometrically frustrated {Fe12} spin cluster.
Graham K, Douglas FJ, Mathieson JS, Moggach SA, Schnack J, Murrie M., Dalton Trans 40(45), 2011
PMID: 21915427
Magnetic aligned vesicles.
Fan D, Hao J., J Colloid Interface Sci 342(1), 2010
PMID: 19931867
Porous capsules {(M)M(5)}(12)Fe(III) (30) (M=Mo(VI), W(VI)): sphere surface supramolecular chemistry with 20 ammonium ions, related solution properties, and tuning of magnetic exchange interactions.
Todea AM, Merca A, Bögge H, Glaser T, Pigga JM, Langston ML, Liu T, Prozorov R, Luban M, Schröder C, Casey WH, Müller A., Angew Chem Int Ed Engl 49(3), 2010
PMID: 20013836
Spin freezing and slow magnetization dynamics in geometrically frustrated magnetic molecules with exchange disorder.
Schröder C, Fang X, Furukawa Y, Luban M, Prozorov R, Borsa F, Kumagai K., J Phys Condens Matter 22(21), 2010
PMID: 21393733
Level crossings and zero-field splitting in the {Cr8}-cubane spin cluster studied using inelastic neutron scattering and magnetization.
Vaknin D, Garlea VO, Demmel F, Mamontov E, Nojiri H, Martin C, Chiorescu I, Qiu Y, Kögerler P, Fielden J, Engelhardt L, Rainey C, Luban M., J Phys Condens Matter 22(46), 2010
PMID: 21403379
Magnetic {Mo72Fe30}-embedded hybrid nanocapsules.
Cui J, Fan D, Hao J., J Colloid Interface Sci 330(2), 2009
PMID: 19027122
Electronic control of spin coupling in keplerate-type polyoxomolybdates.
Botar B, Ellern A, Hermann R, Kögerler P., Angew Chem Int Ed Engl 48(48), 2009
PMID: 19859930
Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M5}12V30 Keplerates (M = Mo, W).
Todea AM, Merca A, Bögge H, Glaser T, Engelhardt L, Prozorov R, Luban M, Müller A., Chem Commun (Camb) (23), 2009
PMID: 19503867
Molecular nanomagnets and magnetic nanoparticles: the EMR contribution to a common approach.
Fittipaldi M, Sorace L, Barra AL, Sangregorio C, Sessoli R, Gatteschi D., Phys Chem Chem Phys 11(31), 2009
PMID: 19639130
Polyoxometalate-mediated self-assembly of single-molecule magnets: {[XW9O34]2[Mn(III)4Mn(II)2O4(H2O)4]}12-.
Ritchie C, Ferguson A, Nojiri H, Miras HN, Song YF, Long DL, Burkholder E, Murrie M, Kögerler P, Brechin EK, Cronin L., Angew Chem Int Ed Engl 47(30), 2008
PMID: 18574836
Hybrid host-guest complexes: directing the supramolecular structure through secondary host-guest interactions.
Streb C, McGlone T, Brücher O, Long DL, Cronin L., Chemistry 14(29), 2008
PMID: 18780383
Kagome network compounds and their novel magnetic properties.
Pati SK, Rao CN., Chem Commun (Camb) (39), 2008
PMID: 18830461
Extending the {(Mo)MO5}12M30 capsule keplerate sequence: a {Cr30} cluster of S=3/2 metal centers with a {Na(H2O)12} encapsulate.
Todea AM, Merca A, Bögge H, van Slageren J, Dressel M, Engelhardt L, Luban M, Glaser T, Henry M, Müller A., Angew Chem Int Ed Engl 46(32), 2007
PMID: 17628480
Nanometer-sized molybdenum-iron oxide capsule-surface modifications: external and internal.
Müller A, Bögge H, Sousa FL, Schmidtmann M, Kurth DG, Volkmer D, van Slageren J, Dressel M, Kistler ML, Liu T., Small 3(6), 2007
PMID: 17385209
Highly anisotropic orbitally dependent superexchange in cyano-bridged clusters containing Mn(III) and Mn(II) ions.
Palii A, Ostrovsky SM, Klokishner SI, Tsukerblat BS, Dunbar KR., Chemphyschem 7(4), 2006
PMID: 16596610
Towards polyoxometalate-integrated nanosystems.
Long DL, Cronin L., Chemistry 12(14), 2006
PMID: 16416497
Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers.
Abbas H, Pickering AL, Long DL, Kögerler P, Cronin L., Chemistry 11(4), 2005
PMID: 15660354
Asymmetric terminal ligation on substituted sites in a disorder-free Keggin anion, [beta-SiFe2W10O36(OH)2(H2O)Cl]5-.
Botar B, Geletii YV, Kögerler P, Musaev DG, Morokuma K, Weinstock IA, Hill CL., Dalton Trans (11), 2005
PMID: 15909053
[{(Mo)Mo5O21(H2O)3(SO4)}12(VO)30(H2O)20]36-: a molecular quantum spin icosidodecahedron.
Botar B, Kögerler P, Hill CL., Chem Commun (Camb) (25), 2005
PMID: 15968350
Triangular geometrical and magnetic motifs uniquely linked on a spherical capsule surface.
Müller A, Todea AM, van Slageren J, Dressel M, Bögge H, Schmidtmann M, Luban M, Engelhardt L, Rusu M., Angew Chem Int Ed Engl 44(25), 2005
PMID: 15915530
Ferrimagnetically ordered nanosized polyoxomolybdate-based cluster spheres.
Botar B, Kögerler P, Müller A, Garcia-Serres R, Hill CL., Chem Commun (Camb) (45), 2005
PMID: 16292368

30 References

Daten bereitgestellt von Europe PubMed Central.

Macroscopic measurement of resonant magnetization tunneling in high-spin molecules.
Friedman JR, Sarachik MP, Tejada J, Ziolo R., Phys. Rev. Lett. 76(20), 1996
PMID: 10061120

Sessoli, Nature 365(), 1993

Thomas, Nature 383(), 1996

Gatteschi, Chem. Commun. (), 2000

Dearden, Angew. Chem. 113(), 2001

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 40(), 2001

Müller, Struct. Bonding (Berlin) 96(), 2000

Müller, Chem. Commun. (), 1999
Polyoxometalates: Very Large Clusters-Nanoscale Magnets.
Muller A, Peters F, Pope MT, Gatteschi D., Chem. Rev. 98(1), 1998
PMID: 11851505

Müller, Angew. Chem. 111(), 1999

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 38(), 1999

Müller, Angew. Chem. 112(), 2000

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 39(), 2000

Müller, Angew. Chem. 112(), 2000

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 39(), 2000

Müller, Solid State Sci. 2(), 2000
Relation of collective observables to nuclear shapes.
Zhang J, Casten RF, Zamfir NV., Phys. Rev., C Nucl. Phys. 48(1), 1993
PMID: 9968856

Schnack, Phys. Rev. B 63(), 2001

AUTHOR UNKNOWN, 0

Coxeter, 1973

Müller, Inorg. Chim. Acta 271(), 1998

Gatteschi, Inorg. Chem. 35(), 1996

Fisher, Am. J. Phys. 32(), 1964

Luscombe, J. Chem. Phys. 108(), 1998

Kusnezov, Ann. Phys. N.Y. 204(), 1990

Nosé, J. Chem. Phys. 81(), 1984

Schröder, 0

Axenovich, Phys. Rev. B 63(), 2001

AUTHOR UNKNOWN, 0

Mentrup, Physica A 272(), 1999

Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

Quellen

PMID: 23686989
PubMed | Europe PMC

Suchen in

Google Scholar