Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry

Letzel M, Agena C, Mattay J (2002)
JOURNAL OF MASS SPECTROMETRY 37(1): 63-68.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
Resorc[4]arenes are compounds with interesting properties, mainly because of their ability to form host-guest complexes with the guest located inside the cavity. The size of the guest limits the complexation, as shown by a competition experiment with tetraalkylammonium ions of different size. By electroscopy lionization tandem mass spectrometric experiments on resorc[4]arene heterodimers bearing an alkali metal ion as guest, it was found that there must be two different binding mechanisms for alkali metal ions with high surface charge density (Li+ and Na+) on the one hand compared with those with a lower surface charge density on the other hand (K+, Rb+, Cs+). Copyright (C) 2001 John Wiley Sons, Ltd.
Stichworte
relative complex stability; electrospray mass; heterodimer and homodimer complexes; spectrometry; resorc[4]arenes
Erscheinungsjahr
2002
Zeitschriftentitel
JOURNAL OF MASS SPECTROMETRY
Band
37
Ausgabe
1
Seite(n)
63-68
ISSN
1076-5174
eISSN
1096-9888
Page URI
https://pub.uni-bielefeld.de/record/1615393

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Letzel M, Agena C, Mattay J. Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry. JOURNAL OF MASS SPECTROMETRY. 2002;37(1):63-68.
Letzel, M., Agena, C., & Mattay, J. (2002). Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry. JOURNAL OF MASS SPECTROMETRY, 37(1), 63-68. https://doi.org/10.1002/jms.247
Letzel, Matthias, Agena, C, and Mattay, Jochen. 2002. “Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry”. JOURNAL OF MASS SPECTROMETRY 37 (1): 63-68.
Letzel, M., Agena, C., and Mattay, J. (2002). Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry. JOURNAL OF MASS SPECTROMETRY 37, 63-68.
Letzel, M., Agena, C., & Mattay, J., 2002. Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry. JOURNAL OF MASS SPECTROMETRY, 37(1), p 63-68.
M. Letzel, C. Agena, and J. Mattay, “Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry”, JOURNAL OF MASS SPECTROMETRY, vol. 37, 2002, pp. 63-68.
Letzel, M., Agena, C., Mattay, J.: Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry. JOURNAL OF MASS SPECTROMETRY. 37, 63-68 (2002).
Letzel, Matthias, Agena, C, and Mattay, Jochen. “Investigation of homo- and heterodimer alkali metal cation complexes of resorc[4]arenes by electrospray ionization mass spectrometry”. JOURNAL OF MASS SPECTROMETRY 37.1 (2002): 63-68.

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