Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene
Mormann M, Kuck D (2002)
JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS 45(7): 601-610.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Mormann, Michael;
Kuck, DietmarUniBi
Abstract / Bemerkung
An efficient synthesis of [1-C-13]-para-xylene (1a) and [2-C-13]-para-xylene (1b) is described. The incorporation of the label has been achieved by cyclocondensation of suitable 1,5-bis(bromomagnesio)alkanes with either ethyl [1-C-13]acetate or ethyl [C-13]formate which gave [ring-C-13]-labelled dimethylcyclohexanols. Dehydration of these alcohols followed by dehydrogenation of the intermediate dimethylcyclohexenes furnished the title compounds in 32 and 40% overall yield, respectively. Copyright (C) 2002 John Wiley Sons, Ltd.
Stichworte
arenium ions;
[2-C-13]-para-xylene;
[1-C-13]-para-xylene;
carbon scrambling;
carbon-13 labelled arenes;
gaseous
Erscheinungsjahr
2002
Zeitschriftentitel
JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS
Band
45
Ausgabe
7
Seite(n)
601-610
ISSN
0362-4803
eISSN
1099-1344
Page URI
https://pub.uni-bielefeld.de/record/1614133
Zitieren
Mormann M, Kuck D. Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene. JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS. 2002;45(7):601-610.
Mormann, M., & Kuck, D. (2002). Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene. JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 45(7), 601-610. https://doi.org/10.1002/jlcr.584
Mormann, Michael, and Kuck, Dietmar. 2002. “Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene”. JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS 45 (7): 601-610.
Mormann, M., and Kuck, D. (2002). Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene. JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS 45, 601-610.
Mormann, M., & Kuck, D., 2002. Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene. JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 45(7), p 601-610.
M. Mormann and D. Kuck, “Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene”, JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, vol. 45, 2002, pp. 601-610.
Mormann, M., Kuck, D.: Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene. JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS. 45, 601-610 (2002).
Mormann, Michael, and Kuck, Dietmar. “Synthesis of [1-C-13]-para-xylene and [2-C-13]-para-xylene”. JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS 45.7 (2002): 601-610.
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Suchen in
Google Scholar