Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins
Rimkus A, Sewald N (2002)
Organic Letters 4(19): 3289-3291.
Zeitschriftenaufsatz
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Autor*in
Rimkus, A;
Sewald, NorbertUniBi 
Einrichtung
Abstract / Bemerkung
The copper-catalyzed conjugate addition of symmetrical and mixed diorganozinc compounds as well as functionalized diorganozinc cuprates to nitroolefins leads to synthetically versatile nitro compounds in moderate to good yields. Mixed TMSM-organozinc compounds are suitable reagents for conjugate addition, since the TMSM group is not being transferred. Ipso substitution is observed in the absence of a catalytic amount of copper(I) salt. The nitroalkene moiety in 3-nitroacrylates proved to be the predominant Michael acceptor.
Erscheinungsjahr
2002
Zeitschriftentitel
Organic Letters
Band
4
Ausgabe
19
Seite(n)
3289-3291
ISSN
1523-7060
eISSN
1523-7052
Page URI
https://pub.uni-bielefeld.de/record/1613647
Zitieren
Rimkus A, Sewald N. Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins. Organic Letters. 2002;4(19):3289-3291.
Rimkus, A., & Sewald, N. (2002). Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins. Organic Letters, 4(19), 3289-3291. https://doi.org/10.1021/ol026557w
Rimkus, A, and Sewald, Norbert. 2002. “Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins”. Organic Letters 4 (19): 3289-3291.
Rimkus, A., and Sewald, N. (2002). Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins. Organic Letters 4, 3289-3291.
Rimkus, A., & Sewald, N., 2002. Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins. Organic Letters, 4(19), p 3289-3291.
A. Rimkus and N. Sewald, “Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins”, Organic Letters, vol. 4, 2002, pp. 3289-3291.
Rimkus, A., Sewald, N.: Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins. Organic Letters. 4, 3289-3291 (2002).
Rimkus, A, and Sewald, Norbert. “Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins”. Organic Letters 4.19 (2002): 3289-3291.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
3 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
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