Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules
Bielanski A, Malecka-Lubanska A, Micek-Ilnicka A, Müller A, Diemann E (2002)
INORGANICA CHIMICA ACTA 338: 7-12.
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Abstract / Bemerkung
Derivatographic analysis (TG, DTA and DTG) coupled with mass spectrometry, FTIR spectroscopy as well as water sorption experiments were used to study the thermal properties of (NH4)(32) [Mo-110(VI) Mo-28(V) O-416 H-6 (H2O)(58) (CH3COO)(6)]. approximately 250 H2O (1) exhibiting the nanosized 'giant wheel' anion. The particular stages of sample transformations are discussed and compared with the known single crystal X-ray structure of (1). The giant wheel type clusters appear approximately to be stable up to 350 degreesC. Interestingly, the complex system can be formally considered as a nanostructured landscape embedded in an 'ocean' of water molecules. (C) 2002 Elsevier Science B.V. All rights reserved.
Stichworte
polyoxometalates;
supramolecular chemistry;
nanosized clusters
Erscheinungsjahr
2002
Zeitschriftentitel
INORGANICA CHIMICA ACTA
Band
338
Seite(n)
7-12
ISSN
0020-1693
Page URI
https://pub.uni-bielefeld.de/record/1613393
Zitieren
Bielanski A, Malecka-Lubanska A, Micek-Ilnicka A, Müller A, Diemann E. Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules. INORGANICA CHIMICA ACTA. 2002;338:7-12.
Bielanski, A., Malecka-Lubanska, A., Micek-Ilnicka, A., Müller, A., & Diemann, E. (2002). Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules. INORGANICA CHIMICA ACTA, 338, 7-12. https://doi.org/10.1016/S0020-1693(02)00874-5
Bielanski, A, Malecka-Lubanska, A, Micek-Ilnicka, A, Müller, Achim, and Diemann, Ekkehard. 2002. “Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules”. INORGANICA CHIMICA ACTA 338: 7-12.
Bielanski, A., Malecka-Lubanska, A., Micek-Ilnicka, A., Müller, A., and Diemann, E. (2002). Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules. INORGANICA CHIMICA ACTA 338, 7-12.
Bielanski, A., et al., 2002. Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules. INORGANICA CHIMICA ACTA, 338, p 7-12.
A. Bielanski, et al., “Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules”, INORGANICA CHIMICA ACTA, vol. 338, 2002, pp. 7-12.
Bielanski, A., Malecka-Lubanska, A., Micek-Ilnicka, A., Müller, A., Diemann, E.: Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules. INORGANICA CHIMICA ACTA. 338, 7-12 (2002).
Bielanski, A, Malecka-Lubanska, A, Micek-Ilnicka, A, Müller, Achim, and Diemann, Ekkehard. “Thermal properties of (NH4)(32)[Mo138O416H6(H2O)(58)(CH3COO)(6)].approximately 250H(2)O: on the route to prove the complexity of a nanostructured landscape - especially with different type of H2O ligands - embedded in an 'ocean' of water molecules”. INORGANICA CHIMICA ACTA 338 (2002): 7-12.
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