(Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode

Despagnet-Ayoub E, Sole S, Gornitzka H, Rozhenko AB, Schoeller W, Bourissou D, Bertrand G (2003)
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 125(1): 124-130.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
DOI
Autor*in
Despagnet-Ayoub, E; Sole, S; Gornitzka, H; Rozhenko, AB; Schoeller, WolfgangUniBi; Bourissou, D; Bertrand, G
Einrichtung
Fakultät für Chemie > Theoretische Chemie
Abstract / Bemerkung
A broad range of (phosphino)(aryl)carbenes, 1b-d, 10a,b, and 14a,b, were prepared by photolysis of their diazo precursors. The influence of the steric and electronic properties of the aryl ring on the structure and stability of these carbenes was studied both experimentally and theoretically. Among the different stabilization modes investigated, those featuring an acceptor as well as a spectatoraryl substituent result in stable or at least persistent carbenes that could be completely characterized by classical spectroscopic methods. In marked contrast, the new susbtitution pattern featuring a donor aryl ring results in a very fleeting carbene.
Erscheinungsjahr
2003
Zeitschriftentitel
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Band
125
Ausgabe
1
Seite(n)
124-130
ISSN
0002-7863
eISSN
1520-5126
Page URI
https://pub.uni-bielefeld.de/record/1612760

Zitieren

Despagnet-Ayoub E, Sole S, Gornitzka H, et al. (Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2003;125(1):124-130.
Despagnet-Ayoub, E., Sole, S., Gornitzka, H., Rozhenko, A. B., Schoeller, W., Bourissou, D., & Bertrand, G. (2003). (Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(1), 124-130. https://doi.org/10.1021/ja0281986
Despagnet-Ayoub, E, Sole, S, Gornitzka, H, Rozhenko, AB, Schoeller, Wolfgang, Bourissou, D, and Bertrand, G. 2003. “(Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode”. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 125 (1): 124-130.
Despagnet-Ayoub, E., Sole, S., Gornitzka, H., Rozhenko, A. B., Schoeller, W., Bourissou, D., and Bertrand, G. (2003). (Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 125, 124-130.
Despagnet-Ayoub, E., et al., 2003. (Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125(1), p 124-130.
E. Despagnet-Ayoub, et al., “(Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode”, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 125, 2003, pp. 124-130.
Despagnet-Ayoub, E., Sole, S., Gornitzka, H., Rozhenko, A.B., Schoeller, W., Bourissou, D., Bertrand, G.: (Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 125, 124-130 (2003).
Despagnet-Ayoub, E, Sole, S, Gornitzka, H, Rozhenko, AB, Schoeller, Wolfgang, Bourissou, D, and Bertrand, G. “(Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode”. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 125.1 (2003): 124-130.

4 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Syntheses, structural characterisation and electronic structures of some simple acyclic amino carbene complexes.
Eaves SG, Yufit DS, Skelton BW, Howard JA, Low PJ., Dalton Trans 44(32), 2015
PMID: 26199183
A persistent (amino)(ferrocenyl)carbene().
Dehope A, Mendoza-Espinosa D, Donnadieu B, Bertrand G., New J Chem 35(10), 2011
PMID: 22707878
A Brief Survey of our Contribution to Stable Carbene Chemistry.
Martin D, Melaimi M, Soleilhavoup M, Bertrand G., Organometallics 30(20), 2011
PMID: 22707843
Heterocyclic carbenes: synthesis and coordination chemistry.
Hahn FE, Jahnke MC., Angew Chem Int Ed Engl 47(17), 2008
PMID: 18398856

References

Daten bereitgestellt von Europe PubMed Central.

Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 12515513
PubMed | Europe PMC

Suchen in

Google Scholar