On the donor ability of the phosphaneiminato substituent and cube formation with transition metal fragments

Schoeller W (2003)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 629(5): 816-827.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The particular role of the phosphaneiminato ligand as a donor is investigated for a) nitrenes (phosphinidenes) and carbenes and b) cubane formation with transition metals. Accordingly, and as shown for the case a) the ligand is a stronger pi-donor than an amino group and can be considered as a special case of imine-type substituents. The latter are very effective in pi-donation. In the case b), i.e. the cubane formation with transition metals, one has to consider transition metals with a partially or completely filled d-shell (with electrons). Hence depending on the transition metal, cubanes are build with weak ferromagnetic coupled or closed shell systems. For the cubanes with closed shell character the matter of insertion of halide anions is discussed. In the last chapter of the review the bond stretching in the dithionitrosyl complexes with thenium is characterized.
Stichworte
phosphane iminato substitution; quantum chemical; investigations; cage formation; density functional calculations
Erscheinungsjahr
2003
Zeitschriftentitel
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Band
629
Ausgabe
5
Seite(n)
816-827
ISSN
0044-2313
eISSN
1521-3749
Page URI
https://pub.uni-bielefeld.de/record/1611472

Zitieren

Schoeller W. On the donor ability of the phosphaneiminato substituent and cube formation with transition metal fragments. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 2003;629(5):816-827.
Schoeller, W. (2003). On the donor ability of the phosphaneiminato substituent and cube formation with transition metal fragments. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 629(5), 816-827. doi:10.1002/zaac.200390143
Schoeller, W. (2003). On the donor ability of the phosphaneiminato substituent and cube formation with transition metal fragments. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 629, 816-827.
Schoeller, W., 2003. On the donor ability of the phosphaneiminato substituent and cube formation with transition metal fragments. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 629(5), p 816-827.
W. Schoeller, “On the donor ability of the phosphaneiminato substituent and cube formation with transition metal fragments”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 629, 2003, pp. 816-827.
Schoeller, W.: On the donor ability of the phosphaneiminato substituent and cube formation with transition metal fragments. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 629, 816-827 (2003).
Schoeller, Wolfgang. “On the donor ability of the phosphaneiminato substituent and cube formation with transition metal fragments”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 629.5 (2003): 816-827.