Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph)
Malisch W, Schumacher D, Schmiedeskamp B, Jehle H, Eisner D, Schoeller W, Nieger M (2003)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (11): 2133-2138.
Zeitschriftenaufsatz
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Autor*in
Malisch, W;
Schumacher, D;
Schmiedeskamp, B;
Jehle, H;
Eisner, D;
Schoeller, WolfgangUniBi;
Nieger, M
Einrichtung
Abstract / Bemerkung
The trialkylgallanes GaR"(3) [R' = Me, iPr (2a and 2b)] react with the ferrio-silanols Cp(OC)(2)Fe-Si(R)(R')OH [R = R' = Me, iPr, Ph (1a-c), R = Me, R' = Ph (1d)] by alkane elimination to yield the iron-substituted siloxy-gallanes [Cp(OC)(2)Fe-Si-(R)(R')OGaR"(2)](2) (3a-e). According to molecular mass determination in benzene (3a, 3b, 3d), X-ray analyses (3a, 3d) and NMR spectroscopy (3e), the novel hetero-siloxanes exist as dimers both in solution and in the solid state. The bonding situation and geometry of the ferrio-heterosiloxane [Cp(OC)(2)Fe-SiH2OGaH2](2) has been analyzed by density functional calculation. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
Stichworte
gallium;
silanols;
silicon;
siloxanes;
iron
Erscheinungsjahr
2003
Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Ausgabe
11
Seite(n)
2133-2138
ISSN
1434-1948
Page URI
https://pub.uni-bielefeld.de/record/1611094
Zitieren
Malisch W, Schumacher D, Schmiedeskamp B, et al. Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2003;(11):2133-2138.
Malisch, W., Schumacher, D., Schmiedeskamp, B., Jehle, H., Eisner, D., Schoeller, W., & Nieger, M. (2003). Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(11), 2133-2138.
Malisch, W, Schumacher, D, Schmiedeskamp, B, Jehle, H, Eisner, D, Schoeller, Wolfgang, and Nieger, M. 2003. “Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph)”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no. 11: 2133-2138.
Malisch, W., Schumacher, D., Schmiedeskamp, B., Jehle, H., Eisner, D., Schoeller, W., and Nieger, M. (2003). Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2133-2138.
Malisch, W., et al., 2003. Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (11), p 2133-2138.
W. Malisch, et al., “Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph)”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, pp. 2133-2138.
Malisch, W., Schumacher, D., Schmiedeskamp, B., Jehle, H., Eisner, D., Schoeller, W., Nieger, M.: Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2133-2138 (2003).
Malisch, W, Schumacher, D, Schmiedeskamp, B, Jehle, H, Eisner, D, Schoeller, Wolfgang, and Nieger, M. “Iron-fragment-substituted heterosiloxanes of gallium [Cp(OC)(2)Fe-SiR2OGaR'(2)](2) (R, R' = alkyl, aryl) - Structures of [Cp(OC)(2)Fe-SiR2OGaMe2](2) (R = Me, Ph)”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 11 (2003): 2133-2138.
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