High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15
Vongtragool S, Gorshunov B, Mukhin AA, van Slageren J, Dressel M, Müller A (2003)
PHYSICAL CHEMISTRY CHEMICAL PHYSICS 5(13): 2778-2782.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Vongtragool, S;
Gorshunov, B;
Mukhin, AA;
van Slageren, J;
Dressel, M;
Müller, AchimUniBi ![](https://pub.uni-bielefeld.de/images/icon_orcid.png)
![](https://pub.uni-bielefeld.de/images/icon_orcid.png)
Einrichtung
Abstract / Bemerkung
A novel type of high-frequency magnetic resonance spectroscopy was used to investigate magnetic excitations of the molecular magnetic cluster V-15 in the frequency range from 1.5 cm(-1) to 10 cm(-1), at low temperatures, between 2.5 K and 30 K. In the optical transmission spectra, we observed absorption lines over a wide range of magnetic fields up to 6.5 T, which correspond to the Zeeman splitting of the low-lying spin states. Our frequency-domain technique, and advanced data analysis allow accurate determination of the principal values of the anisotropic g tensor, and other mode parameters, even for powder samples. The g values were obtained as gparallel toc = 1.981 +/- 0.003 and g(perpendicular toc) = 1.953 +/- 0.003, while the intrinsic linewidth was found to be Deltanu = 0.02 - 0.035 cm(-1) ( 210 - 370 Oe). The temperature dependence of Deltamu, the mode contribution to the magnetic permeability, is in good agreement with theory.
Erscheinungsjahr
2003
Zeitschriftentitel
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Band
5
Ausgabe
13
Seite(n)
2778-2782
ISSN
1463-9076
eISSN
1463-9084
Page URI
https://pub.uni-bielefeld.de/record/1610877
Zitieren
Vongtragool S, Gorshunov B, Mukhin AA, van Slageren J, Dressel M, Müller A. High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15. PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 2003;5(13):2778-2782.
Vongtragool, S., Gorshunov, B., Mukhin, A. A., van Slageren, J., Dressel, M., & Müller, A. (2003). High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 5(13), 2778-2782. https://doi.org/10.1039/b302244g
Vongtragool, S, Gorshunov, B, Mukhin, AA, van Slageren, J, Dressel, M, and Müller, Achim. 2003. “High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15”. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 5 (13): 2778-2782.
Vongtragool, S., Gorshunov, B., Mukhin, A. A., van Slageren, J., Dressel, M., and Müller, A. (2003). High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 5, 2778-2782.
Vongtragool, S., et al., 2003. High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 5(13), p 2778-2782.
S. Vongtragool, et al., “High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15”, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 5, 2003, pp. 2778-2782.
Vongtragool, S., Gorshunov, B., Mukhin, A.A., van Slageren, J., Dressel, M., Müller, A.: High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15. PHYSICAL CHEMISTRY CHEMICAL PHYSICS. 5, 2778-2782 (2003).
Vongtragool, S, Gorshunov, B, Mukhin, AA, van Slageren, J, Dressel, M, and Müller, Achim. “High-frequency magnetic spectroscopy on the molecular magnetic cluster V-15”. PHYSICAL CHEMISTRY CHEMICAL PHYSICS 5.13 (2003): 2778-2782.
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