Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems
Schoeller W (2003)
NEW ASPECTS IN PHOSPHORUS CHEMISTRY III 229: 75-94.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Einrichtung
Abstract / Bemerkung
Cationic low-coordinated pi-bonded phosphorus compounds add Lewis donors, such as amines or phosphines. In contrast to the trigonal bipyramide formed in donor-addition to the siliconium cation, the phosphorus cations add donors in a perpendicular fashion, depending on the nature of the pi-bonds toward phosphorus. According to quantum chemical calculations the various cations reveal different stabilities and hence a strong variation in donor addition abilities.
Stichworte
low-coordinated phosphorus systems;
donor-addition;
mono- and bis-coordination;
cations;
pi-bonded;
bipyramide formation
Erscheinungsjahr
2003
Zeitschriftentitel
NEW ASPECTS IN PHOSPHORUS CHEMISTRY III
Band
229
Seite(n)
75-94
ISSN
0
Page URI
https://pub.uni-bielefeld.de/record/1610120
Zitieren
Schoeller W. Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems. NEW ASPECTS IN PHOSPHORUS CHEMISTRY III. 2003;229:75-94.
Schoeller, W. (2003). Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems. NEW ASPECTS IN PHOSPHORUS CHEMISTRY III, 229, 75-94. https://doi.org/10.1007/b11151
Schoeller, Wolfgang. 2003. “Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems”. NEW ASPECTS IN PHOSPHORUS CHEMISTRY III 229: 75-94.
Schoeller, W. (2003). Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems. NEW ASPECTS IN PHOSPHORUS CHEMISTRY III 229, 75-94.
Schoeller, W., 2003. Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems. NEW ASPECTS IN PHOSPHORUS CHEMISTRY III, 229, p 75-94.
W. Schoeller, “Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems”, NEW ASPECTS IN PHOSPHORUS CHEMISTRY III, vol. 229, 2003, pp. 75-94.
Schoeller, W.: Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems. NEW ASPECTS IN PHOSPHORUS CHEMISTRY III. 229, 75-94 (2003).
Schoeller, Wolfgang. “Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems”. NEW ASPECTS IN PHOSPHORUS CHEMISTRY III 229 (2003): 75-94.
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